Although Dmitri Mendeleev is often considered the "father" of the periodic table, the work of many scientists contributed to its present form. In the Beginning
A necessary prerequisite to the construction of the periodic table was the discovery of the individual elements. Although elements such as gold, silver, tin, copper, lead and mercury have been known since antiquity, the first scientific discovery of an element occurred in 1649 when Hennig Brand discovered phosphorous. During the next 200 years, a vast body of knowledge concerning the properties of elements and their compounds was acquired by chemists (a 1790 article on the elements). By 1869, a total of 63 elements had been discovered. As the number of known elements grew, scientists began to recognize patterns in properties and began to develop classification schemes.
Law of Triads
In 1817 Johann Dobereiner noticed that the atomic weight of strontium fell midway between the weights of calcium and barium, elements possessing similar chemical properties. In 1829, after discovering the halogen triad composed of chlorine, bromine, and iodine and the alkali metal triad of lithium, sodium and potassium he proposed that nature contained triads of elements the middle element had properties that were an average of the other two members when ordered by the atomic weight (the Law of Triads).

This new idea of triads became a popular area of study. Between 1829 and 1858 a number of scientists (Jean Baptiste Dumas, Leopold Gmelin, Ernst Lenssen, Max von Pettenkofer, and J.P. Cooke) found that these types of chemical relationships extended beyond the triad. During this time fluorine was added to the halogen group; oxygen, sulfur,selenium and tellurium were grouped into a family while nitrogen, phosphorus, arsenic, antimony, and bismuth were classified as another. Unfortunately, research in this area was hampered