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Analytical Chemistry

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Analytical chemistry

What is Qualitative Analysis?
Qualitative analysis is the aspect of analytical chemistry dealing with the identification of elements or compounds in an unknown substance. Very simply put, it answers the question "What is in this sample?" and usually does so with yes/no question.

What is Quantitative Analysis?
Quantitative chemical analysis is the aspect of analytical chemistry dealing with determining the quantity of a particular chemical is in a substance. In short, it attempts to answer questions involving "How much?"

Accuracy: Accuracy refers to the agreement between experimental data and a known value. You can think of it in terms of a bull’s eye in which the target is hit close to the center, yet the marks in the target aren't necessarily close to each other.
Accuracy is defined as, "The ability of a measurement to match the actual value of the quantity being measured". If in reality it is 34.0 F outside and a temperature sensor reads 34.0 F, then than sensor is accurate.

Precision Precision refers to how well experimental values agree with each other. If you hit a bull’s-eye precisely, then you are able to hit the same spot on the target each time, even though that spot may be distant from the center.
Precision is defined as, "(1) The ability of a measurement to be consistently reproduced" and "(2) The number of significant digits to which a value has been reliably measured". If on several tests the temperature sensor matches the actual temperature while the actual temperature is held constant, then the temperature sensor is precise. By the second definition, the number 3.1415 is more precise than the number 3.14
Examples:
Example of a sensor with BAD accuracy and BAD precision: Suppose a lab refrigerator holds a constant temperature of 38.0 F. A temperature sensor is tested 10 times in the refrigerator. The temperatures from the test yield the temperatures of: 39.4, 38.1, 39.3, 37.5, 38.3, 39.1, 37.1, 37.8, 38.8, 39.0. This distribution shows no tendency toward a particular value (lack of precision) and does not acceptably match the actual temperature (lack of accuracy).

Example of a sensor with GOOD accuracy and BAD precision:
Suppose a lab refrigerator holds a constant temperature of 38.0 F. A temperature sensor is tested 10 times in the refrigerator. The temperatures from the test yield the temperatures of: 37.8, 38.3, 38.1, 38.0, 37.6, 38.2, 38.0, 38.0, 37.4, 38.3. This distribution shows no impressive tendency toward a particular value (lack of precision) but each value does come close to the actual temperature (high accuracy).

Example of a sensor with BAD accuracy and GOOD precision: Suppose a lab refrigerator holds a constant temperature of 38.0 F. A temperature sensor is tested 10 times in the refrigerator. The temperatures from the test yield the temperatures of : 39.2, 39.3, 39.1, 39.0, 39.1, 39.3, 39.2, 39.1, 39.2, 39.2. This distribution does show a tendency toward a particular value (high precision) but every measurement is well off from the actual temperature (low accuracy).

Example of a sensor with GOOD accuracy and GOOD precision: Suppose a lab refrigerator holds a constant temperature of 38.0 F. A temperature sensor is tested 10 times in the refrigerator. The temperatures from the test yield the temperatures of: 38.0, 38.0, 37.8, 38.1, 38.0, 37.9, 38.0, 38.2, 38.0, 37.9. This distribution does show a tendency toward a particular value (high precision) and is very near the actual temperature each time (high accuracy).

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