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Chemistry F321

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AS Chemistry

NAME

1.2.1 Electron Structure Exam Questions
1. Electrons are arranged in energy levels. (a) An orbital is a region in which an electron may be found. Draw diagrams to show the shape of an s orbital and of a p orbital.

s orbital

p orbital
[2]

(b)

Complete the table below to show how many electrons completely fill each of the following. number of electrons a d orbital a p sub-shell the third shell (n = 3)
[3]

(c)

The energy diagram below is for the eight electrons in an oxygen atom. The diagram is incomplete as it only shows the two electrons in the 1s level.

energy

1s

Complete the diagram for the oxygen atom by: (i) (ii) adding labels for the other sub-shell levels adding arrows to show how the other electrons are arranged.
[2]

1 Greenhead College

AS Chemistry

NAME

2. (a) Complete the electronic configuration of carbon 1s2 .................................................................................................................... (b) (i) Complete the electronic configuration of a bromine atom. 1s22s22p63s23p6.............................................................................................

[1]

[2]

(ii)

Why is bromine classified as a p-block element? ....................................................................................................................... ....................................................................................................................
[1]

(c) Complete the electronic configuration of a potassium ion (K+) 1s2 .................................................................................................................... (d) Complete the electronic configuration of a titanium atom. 1s22s22p6.................................................................................................................
[1] [1]

3. The Periodic Table is a table of elements arranged in order of atomic number. The elements are classified into blocks. (i) State what is meant by the term atomic number. .......................................................................................................................
[1]

(ii)

Identify the seventh element in the fourth period. State which block this element is in. element ................................................ block .................................................
[1]

4. Modern plasma television screens emit light when mixtures of noble gases, such as neon and xenon, are ionised. The first ionisation energies of neon and xenon are shown in the table below. 1st ionisation energy / kJ mol–1 +2081 +1170

element neon xenon

2 Greenhead College

AS Chemistry Explain why xenon has a lower first ionisation energy than neon.

NAME

................................................................................................................................. ................................................................................................................................. ................................................................................................................................. ................................................................................................................................. ................................................................................................................................. ................................................................................................................................
[Total 3 marks]

5. The first ionisation energies of the elements H to K are shown below. Use this diagram to help with your answers to this question.
2500 He

1st ionisation energy / kJ mol–1

Ne Ar P Mg Si Na 4 5 6 7 8 Al K S

2000 1500 H 1000 500 0 0 1 2 3 9 10 11 12 13 14 15 16 17 18 19 20 atomic number Be B Li C N O F

(a)

Define the term first ionisation energy. ....................................................................................................................... ....................................................................................................................... ....................................................................................................................... .......................................................................................................................
[3]

(b)

Explain why the first ionisation energies show a general increase across Period 2 (Li to Ne). ....................................................................................................................... ....................................................................................................................... .......................................................................................................................
[2]

3 Greenhead College

AS Chemistry

NAME

6. In their reactions, calcium and strontium each lose electrons to form ions with a 2 charge. The first and second ionisation energies of calcium and strontium are shown below. 1st ionisation energy / kJ mol–1 calcium strontium (i) 590 550 2nd ionisation energy / kJ mol–1 1145 1064

Write an equation, with state symbols, to represent the second ionisation energy of calcium. .......................................................................................................................
[2]

(ii)

Why are the second ionisation energies of calcium and strontium greater than their first ionisation energies? ....................................................................................................................... ....................................................................................................................... .......................................................................................................................
[1]

(iii)

Explain why the first and second ionisation energies of strontium are less than those of calcium. ....................................................................................................................... ....................................................................................................................... ....................................................................................................................... ....................................................................................................................... ....................................................................................................................... .......................................................................................................................
[3]

4 Greenhead College

AS Chemistry

NAME

7. Successive ionisation energies provide evidence for the arrangement of electrons in atoms. The table below shows the eight successive ionisation energies of oxygen. ionisation number ionisation energy / kJ mol–1 (i) 1st 1 314 2nd 3 388 3rd 5 301 4th 7 469 5th 10 989 6th 13 327 7th 71 337 8th 84 080

Define the term first ionisation energy. ....................................................................................................................... ....................................................................................................................... ....................................................................................................................... .......................................................................................................................
[3]

(ii)

Write an equation, with state symbols, to represent the third ionisation energy of oxygen. ...................................................................................................................
[2]

(iii)

Explain how the information in the table above provides evidence for two electron shells in oxygen. ....................................................................................................................... ....................................................................................................................... ....................................................................................................................... .......................................................................................................................
[2]

8.

In this question, one mark is available for the quality of use and organisation of scientific terms. Table 1 provides data on elements in Period 2 of the Periodic Table. Table 2 shows the first 6 successive ionisation energies of an element X, which is in Period 3 of the Periodic Table.

5 Greenhead College

AS Chemistry Table 1 element number of protons electron configuration 1st ionisation energy / kJ mol–1 Table 2 element 1st X 578 2nd 1817 ionisation energy / kJ mol–1 3rd 2745 4th 11 578 5th 14 831 Li 3 1s2 2s1 520 Be 4 1s2 2s2 900 B 5 1s2 2s2 2p1 801

NAME

C 6 1s2 2s2 2p2 1086

N 7 1s2 2s2 2p3 1402

6th 18 378

(a) Using Table 1, describe and explain the trend in first ionisation energies shown by the Period 2 elements, Li–N. ........................................................................................................................................ ....................................................................................................................................... ....................................................................................................................................... .................................................................................................................................................... .................................................................................................................................................... .................................................................................................................................................... ....................................................................................................................................... ....................................................................................................................................... .................................................................................................................................................... (b) Using Table 2, identify element X. Explain how you decided on your answer ........................................................................................................................................ ....................................................................................................................................... ....................................................................................................................................... .................................................................................................................................................... ....................................................................................................................................................
[3] [4]

6 Greenhead College

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