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Semiconductor
Semiconductors :- Most of the solids can be placed in one of the two classes: Metals and insulators. Metals are those through which electric charge can easily flow, while insulators are those through which electric charge is difficult to flow. This distinction between the metals and the insulators can be explained on the basis of the number of free electrons in them. Metals have a large number of free electrons which act as charge carriers, while insulators have practically no free electrons.
There are however, certain solids whose electrical conductivity is intermediate between metals and insulators. They are called ‘Semiconductors’. Carbon, silicon and germanium are examples of semi-conductors. In semiconductors the outer most electrons are neither so rigidly bound with the atom as in an insulator, nor so loosely bound as in metal. At absolute zero a semiconductor becomes an ideal insulator.

semiconductors - Theory and Definition
Semiconductors are the materials whose electrical conductivity lies in between metals and insulator. The energy band structure of the semiconductors is similar to the insulators but in their case, the size of the forbidden energy gap is much smaller than that of the insulator. In this class of crystals, the forbidden gap is of the order of about 1ev, and the two energy bands are distinctly separate with no overlapping. At absolute o0, no electron has any energy even to jump the forbidden gap and reach the conduction band. Therefore the substance is an insulator. But when we heat the crystal and thus provide some energy to the atoms and their electrons, it becomes an easy matter for some electrons to jump the small ( 1 ev) energy gap and go to conduction band. Thus at higher temperatures, the crystal becomes a conductors. This is the specific property of the

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