...oil mole ratio (1:6 to 1:24). The synthesis of methyl esters were achieved by an autoclave nitrogen pressurized reactor equipped with a magnetic stirrer and a thermocouple.42 A maximum yield (97%) of methyl ester was obtained at a temperature of 180 °C, 1:15 molar ratio of methanol and oil for a reaction period of 2 hours. The 3 wt% of catalyst amount and 350-360 min-1 agitation speed were fixed respectively to obtain good yields. 2.13. Esterification of free fatty acids in crude palm oil The production of biodiesel from the crude palm oil by the conventional method, using the homogeneous base catalyst contains large amounts of free fatty acid and it also results in the soap formation and thereby reducing the yield of biodiesel. To overcome these problems the free fatty acids need to be esterified to their esters by using an acid catalyst prior to alkaline catalysed transesterification. The sulfated metal oxide was found to be the best catalyst for this purpose due to its high acidic...
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...London School of Engineering and Materials Science Laboratory report writing instructions DEN101 - Fluid Mechanics 1 Flow Rate Measurement Experiment A. Student Student Number: 1234567 Version 2.0, 27 November 2010 Template for Word 97-2003 Abstract This document explains what is expected in your Fluids 1 lab report. The sections that should be covered are outlined and a structure you could follow is proposed. Detailed advice on how to edit the report is given. The document concludes with the marking criteria for this lab report. Table of Contents Abstract 2 1. Introduction 3 1.1. Writing 3 1.2. Editing and formatting 3 1.3. Content of the introduction 4 2. Background and theory 4 3. Apparatus 4 4. Test 4 5. Experimental procedure 4 6. Results 5 7. Discussion 5 8. Conclusions 5 9. References 5 10. Appendix A: Marking criteria 6 Introduction Before starting to write a report, you should think about what is your audience. Am I writing for colleagues who want a lot of detail how it is done, or am I writing for my boss who just wants an executive summary as he has no time for details? In general, there is not a single type of audience and we have to make our writing suitable for the detailed read, as well as the fast perusal. To understand what is required from you in this report, please have a look at the marking criteria in the Appendix. 1 Writing To limit...
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...Chemistry 322b Formal Lab Report 6th November 2015 I. II. Enzymatic Resolution of 1-Phenylethanol and Diastereomer Analysis Objective/Abstract Enzymatic transesterification reaction was performed to study the resolution of diastereomers using 1H-NMR analysis. The stereo-selectivity of acylase I, an enzyme, for a 50:50 racemic mixture of 1-phenylethanol was determined. In the first of a two-step reaction, 1-phenylethanol was reacted with vinyl acetate with the help of acylase I to form an ester, unreacted 1-phenylethanol, and vinyl alcohol. The unreacted 1phenylethanol was separated from the ester by column chromatography and confirmed by thin-layer chromatography (TLC). In the second reaction, the unreacted 1-phenylethanol was reacted with (R)-(-)-acetoxyphenylacetic acid to form a diastereomer ester. In the latter reaction, four different 1-phenylethanol samples were used in order to compare 1HNMR data of the resulting diastereomer esters and determine which enantiomer of the 50:50 racemic mixture was preferred by acylase I. Those four samples were: (1) racemic 1-phenylethanol, (2) unreacted 1-phenylethanol, (3) (R)-1-phenylethanol, and (4) (S)-1phenylethanol. After 1H-NMR analysis, it was found that the (S)-1-phenylethanol was preferred by acylase I. III. Introduction and Background Information Scheme 1: Reaction of 1-phenylethanol with vinyl acetate in the presence of the enzyme acylase I to produce 1-phenylethyl acetate (ester), 1-phenylethanol, and...
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...CH 220C ORGANIC CHEMISTRY LABORATORY Spring, 2015 Section Page 1. General Information 2 2. Safety Information 2 3. Attendance 3 Make-Up Policy 3 4. Laboratory Protocol 3 Assigned Reading 3 Pre-Lab Quizzes 3 Lab Notebook 5 Chemicals 5 Due Dates for Reports 5 5. Orientation 5 In-Lab Information 5 Library Information 5 6. Check-In 6 7. Grading Procedure 6 8. Policy on Cheating 7 9. TA Office Hours 8 10. Faculty Course CoordinatorS 8 11. Course Web Page 8 12. Hints to Minimize Frustration IN ORGANIC CHEMISTRY 8 13. Work Schedule 10 Lab Report Due Date Schedule 10 Experiments 10 14. Supplements 17 A. Extraction of Unknown 17 B. Recrystallization of Unknown Products 18 C. Methyl Benzoate 19 D. Synthesis of Luminol 20 E. Azo Violet 23 1. GENERAL INFORMATION PRE- and CO-REQUISITES Pre- and co-requisites for CH 220C listed in the Course Schedule. Important: Because the lecture and laboratory courses are co-requisites of each other, dropping one of them requires that you drop the other as well, unless the drop occurs during ...
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...16 Upon curing they shrink more as compared to amorphous thermoplastics. Examples are polypropylene (PP), polyethylene (PE) [1]. S. Amin and M. Amin In order to resolve the problem of low thermal and chemical stability of thermoplastic elastomers, dynamic vulcanization techniques were used in late ] plastic. In dynamic vulcanization the thermoplastic and elastomers are both cross-linked and physically mixed together. This gave rise to a second generation of thermoplastic elastomers which had better tensile strength and oil resistance as compared to those formed by physical mixing only [8]. ] ] ] _ were introduced which were made by same dynamic vulcanization process but using natural and butyl rubbers in place of EPR and EPDM. Natural and butyl rubbers have the advantages like low cost, very good over molding properties, reusable and very easily recyclable scrap [9,10]. Butyl rubber based thermoplastic elastomers have excellent adhesion with other thermoplastics hence it is still used to date for many over molding applications [11]. A list of common thermoplastic elastomers used in modern world is given in Table 1. 1.2.2. Amorphous thermoplastics They are usually transparent and have diffused melting point. The molecules are arranged randomly and ] ] _ to crystalline polymers. Upon curing they shrink less as compared to crystalline thermoplastics [3,4]. Examples are polycarbonate (PC), polymethylmethacrylate (PMMA), polystyrene (PS), polyphenylene oxide (PPO), acrylonitrile...
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...GUIDELINES FOR THE CLASSIFICATION AND CODING OF INDUSTRIAL AND HAZARDOUS WASTES TEXAS COMMISSION ON ENVIRONMENTAL QUALITY WASTE PERMITS DIVISION RG-022 Revised 2/05 GUIDELINES FOR THE CLASSIFICATION AND CODING OF INDUSTRIAL AND HAZARDOUS WASTES THIS IS A GUIDANCE DOCUMENT AND SHOULD NOT BE INTERPRETED AS A REPLACEMENT TO THE RULES. The rules for classifying and coding industrial wastes and hazardous wastes may be found in 30 Texas Administrative Code (TAC) Sections (§§) 335.501-.521 (Subchapter R). Prepared by: I&HW Permits Section, MC 130 Waste Permits Division Texas Commission on Environmental Quality P.O. Box 13087 Austin, Texas 78711-3087 RG-022 Texas Commission on Environmental Quality Revised February 2005 i Kathleen Hartnett White, Chairman R. B. “Ralph” Marquez, Commissioner Larry R. Soward, Commissioner Glenn Shankle, Executive Director Authorization for use or reproduction of any original material contained in this publication—that is, not obtained from other sources—is freely granted. The commission would appreciate acknowledgment. Copies of this publication are available for public use through the Texas State Library, other state depository libraries, and the TCEQ Library, in compliance with state depository law. For more information on TCEQ publications call 512/239-0028 or visit our Web site at: http://www.tceq.state.tx.us/publications Published and distributed by the Texas Commission on Environmental Quality PO Box...
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...Action: Binds to an enzyme in the presence of acidic gastric pH, preventing the final transport of hydrogen ions into the gastric lumen (pantoprazole, n.d.). Drug Administration and Dosage: PO (Adults): 40 mg once daily. PO (Children 5 yr): 15– 39 kg— 20 mg once daily for up to 8 wk; 40 kg— 40 mg once daily for up to 8 wk. IV (Adults): 40 mg once daily for 7– 10 days. Gastric Hypersecretory Conditions; PO (Adults): 40 mg twice daily, up to 120 mg twice daily. IV (Adults): 80 mg q 12 hr (up to 240 mg/day) (pantoprazole, n.d.). Drug Interactions: Drug-Drug: Maypabsorption of drugs requiring acid pH, including ketoconazole, itraconazole, atazanavir, ampicillin esters, and iron salts. Mayqrisk of bleeding with warfarin (monitor INR/PT). Hypomagnesemiaqrisk of digoxin toxicity. Mayqmethotrexate levels (pantoprazole, n.d.). Labs effects/ interference: May cause abnormal liver function tests, including increased AST, ALT, alkaline phosphatase, and bilirubin. May cause hypomagnesemia. Monitor serum magnesium prior to and periodically during therapy (pantoprazole, n.d.). Special considerations: Contraindicated in Hypersensitivity; OB: Should be used during pregnancy only if clearly needed; Lactation: Discontinue breast feeding due to potential for serious adverse reactions in infants. Use Cautiously in: Patients using high-doses for 1 year (qrisk of hip, wrist, or spine fractures); Pedi: Safety not established (pantoprazole, n.d.). Potential side effects/Adverse effects/Toxicities: CNS:...
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...Lab Report Marco Huerta Partner: Sami Mrestani Chem 12B – Organic Chemistry 11/07/11 Lazik Benzocaine Objective: To prepare a local anesthetic, Benzocaine, by the direct estherification of p-aminobenzoic acid with ethanol. Abstract: Over the years many new local anesthetics have been synthesized and tested. Though many have not come into general use, the search for the perfect local anesthetic is still under way. An interesting fact about these compounds is that they all share common feature (see general structure below). At one end of the molecule is an aromatic ring. At the other is a secondary or tertiary amine. These two ends are separated by a central chain of atoms usually one to four units long. The aromatic part is typically and ester of an aromatic acid which is important to the bodily detoxification of these compounds. In our experiment, we created a topical anesthetic, Benzocaine, by the direct estherification of p-aminobenzoic acid. This was accomplished by reaction with absolute ethanol catalyzed by concentrated sulfuric acid and later neutralized with a 10% sodium carbonate solution. Neutralization raised the pH of the overall reaction system to about 8 creating a precipitate of Benzocaine. Recrystallization of the crude product was performed to increase purity. Our...
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...Pentachlorophenol (PCP) in wood treatment 1.Introduction Wood is a hard, fibrous structural tissue found in the stems and roots of trees and other woody plants. It has been used for thousands of years for both fuel and as a construction material. It is an organic material, a natural composite of cellulose fibers (which are strong in tension) embedded in a matrix of lignin which resists compression. Wood is sometimes defined as only the secondary xylem in the stems of trees or it is defined more broadly to include the same type of tissue elsewhere such as in the roots of trees or shrubs. In a living tree it performs a support function, enabling woody plants to grow large or to stand up by themselves. It also mediates the transfer of water and nutrients to the leaves and other growing tissues. Wood may also refer to other plant materials with comparable properties, and to material engineered from wood, or wood chips or fiber. The Earth contains about one trillion tonnes of wood, which grows at a rate of 10 billion tonnes per year. As an abundant, carbon-neutral renewable resource, woody materials have been of intense interest as a source of renewable energy. In 1991, approximately 3.5 billion cubic meters of wood were harvested. Dominant uses were for furniture and building construction. The wood-preserving industry treats lumber with various chemicals to protect against insect damage and decay. Chemically preserved wood is used in products for outdoor use such as railway ties...
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...Soldering Air Quality Hazards and Solutions William G. Nicholson U.S. Air Force Abstract Air quality has become questionable with recent increased production and soldering procedures conducted by the Avionics Intermediate Systems Shop at Charleston Air Force Base. With an unknown quality level of air within the soldering area there is a need for a sample to be taken and options to be considered to improve the working environment. Even though the air sample may reveal that levels are under threshold levels, the simple fact that employees are uncomfortable doing the task may warrant solutions as if the sample was above limits. Those changes would not be required by anyone outside of the Air Force, but would be considered based on employee well-being. This research paper will reveal the findings of the air quality sample, the methods of testing, and countermeasures intent on improving air quality. Most research has concluded that the soldering flux is the real contaminate and that the lead based solder does not become airborne during the process; which is exciting in the fact that expanded measures are not needed to account for lead. There are many solutions available to correct the air quality and this paper will assess the most applicable and cost effective. Keywords: soldering, flux, rosin-core, air quality, ventilation Soldering Air Quality Hazards and Solutions The current set-up for soldering avionics component parts has questionable ventilation to account...
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...Available online at www.sciencedirect.com Biotechnology Advances 26 (2008) 246 – 265 www.elsevier.com/locate/biotechadv Research review paper Biological degradation of plastics: A comprehensive review Aamer Ali Shah ⁎, Fariha Hasan, Abdul Hameed, Safia Ahmed Department of Microbiology, Quaid-i-Azam University, Islamabad, Pakistan Received 22 November 2007; received in revised form 31 December 2007; accepted 31 December 2007 Available online 26 January 2008 Abstract Lack of degradability and the closing of landfill sites as well as growing water and land pollution problems have led to concern about plastics. With the excessive use of plastics and increasing pressure being placed on capacities available for plastic waste disposal, the need for biodegradable plastics and biodegradation of plastic wastes has assumed increasing importance in the last few years. Awareness of the waste problem and its impact on the environment has awakened new interest in the area of degradable polymers. The interest in environmental issues is growing and there are increasing demands to develop material which do not burden the environment significantly. Biodegradation is necessary for water-soluble or water-immiscible polymers because they eventually enter streams which can neither be recycled nor incinerated. It is important to consider the microbial degradation of natural and synthetic polymers in order to understand what is necessary for biodegradation and the mechanisms involved. This...
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...DANTES Environmental costs and environmental impacts in a chemical industry eLCC and LCA on two colorants Stefan Bengtsson & Li Sjöborg Product Stewardship & Sustainability Akzo Nobel Surface Chemistry April 2004 Preface This report is the result of our master thesis work at Chalmers University of Technology in Gothenburg. The project was performed at Akzo Nobel Surface Chemistry Sweden and at the department of Environmental System Analysis (ESA) at Chalmers. Sver ker Molander at ESA and Karin Sanne at Akzo Nobel have been the supervisors for this thesis work and we’d like to thank both of them for their support and their many good ideas. Additional thanks goes to the employees at Akzo Nobel Surface Chemistry Support Unit Sweden and to everyone we have been in contact with when collecting data to this thesis. Thank you! Göteborg, May 2004 Stefan Bengtsson Li Sjöborg Summary As the awareness of environmental problems increases so does the demands and guidelines from legislations and customers that deal with the environmental problems of the industries products and manufacturing processes. For a large international chemical company such as Akzo Nobel these increasing demands lead to costs for administrative work, taxes, testing, additional staff and investments. The aim of this study is to determine the properties of these “environmental costs” for the products of a chemical company. The study has focused on the production of two colorants. A surfactant (Berol 09)...
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...Attendance, P4 Lab Schedule, P4 Lab Replacement, P5 Lab Regulation 6.1 General Rules, P5 6.2 Safety Rules, P6 Lab Rules & Regulations on Computer Usage 7.1 ICT Computer Lab, P7 7.2 ICT Internet Lab, P8 Appendix 1 (Lab Replacement Flow Chart), P10 Appendix 2 (Lab Session Replacement Form), P11 Policy for Laboratory Usage after Office Hours, 10.1 Operating Procedure, P12 10.2 Warnings on liability, P12 10.3 Rules and Regulations, P12 Use of Laboratory After Office Hours 11.1 Appendix 3 (Application Form), P14 11.2 Appendix 4 (Student’s Declaration Form), P15 Ambulance Services, P16 Lab Safety Handbook on Chemical Hazards, Physical Hazards and Biological hazards, P17-P64 7 8 9 10 11 13 14 Universiti Tunku Abdul Rahman 2 Definitions • • • • • Lab Session: Time duration allocated for student to do lab experiment. Lab Sheet: A printed material usually contains a series of instructions and information given to the student on how to conduct lab experiment. Lab Report: A written report prepared by student based on individual observation and data analysis after the lab experiment. The format and requirements are usually stated in the lab sheet. Lab Coordinator: A person in charge of coordinating all the lab sessions of the semester and administrating lab matters. Lab Instructor: An academic staff (lecturer or tutor) in charge of the lab session. The lab instructor will give briefing and instructions to students during the lab session. 1. Introduction Practical lab is one...
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...DOTA-K) is described that allows insertion of DOTA at any endo-position within a peptide sequence. Three model pentapeptides were prepared to test the general utility of these derivatives in solid-phase peptide synthesis. Both DOTA derivatives reacted smoothly by means of standard HBTU activation chemistry to the point of insertion of the DOTA amino acid, but extension of the peptide chain beyond the DOTA-amino acid insertion required the use of pre-activated C-pentafluorophenyl ester N-alpha-Fmoc amino acids. Three Gal-80 binding peptides (12-mers) were then prepared by using this methodology with DOTA positioned either at the N terminus or at one of two different internal positions;the binding of the resulting GdDOTA-12-mers to Gal-80 were compared. The methodology described here allows versatile, controlled introduction of DOTA into any location within a peptide sequence. This provides a potential method for the screening of libraries of DOTA-linked peptides for optimal targeting properties This report describes the synthesis and structural characterization of the indium complex of 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid mono(p-aminoanilide) (DOTA-AA), a model compound for 111In-labeled DOTA-biomolecule conjugates. In(DOTA-AA) was prepared by reacting DOTA-AA with 1 equiv of InCl3 in 0.5 M ammonium acetate buffer (pH ∼ 6). It was characterized by spectroscopic methods (IR, ES-MS, and 1H NMR), elemental analysis, and X-ray crystallography. For comparison purposes...
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...Triphenylmethanol Objective: The purpose of this experiment is to synthesize triphenylmethanol from benzophenone via Grignard reaction. The product will be isolated through extractions and purified by recrystallization. Reaction efficiency will be evaluated through percent yield, percent recovery, and the purity of the final product will be determined by IR, TLC, and mp determination. Chemicals: bromobenzene, magnesium turnings, diethyl ether, benzophenone, biphenyl, triphenylmethanol, iodine, 6 M HCl, brine, anhydrous MgSO4 or Na2SO4, 10:90 EtOAc/hexanes. Glassware and equipment: 100 mL RBF, air condenser, Claisen adaptor, 60 and 125 mL addition funnel, short stem glass funnel, two 50 mL Erlenmeyer flasks, 10 mL graduated cylinder, lab jack, crystallizing dish, magnetic stir bar. Techniques: reflux, extraction, vacuum filtration, recrystallization, TLC, mp, IR spectroscopy. Introduction In 1912 Victor Grignard received the Nobel prize in chemistry for his work on the reaction that bears his name, a carbon-carbon bond-forming reaction by which almost any alcohol may be formed from appropriate alkyl halides and carbonyl compounds. The Grignard reagent RMgBr is easily formed by redox reaction of an alkyl halide with magnesium metal in anhydrous diethyl ether solvent. R-Br + Mg → RMgBr The Grignard reagent can be viewed as an ionic species consisting of carbanion R-, with Mg2+ counterion and an additional Br- counterion. The carbanion R- is very reactive, and functions both...
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