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Nanotechnology

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Brussel-Bruxelles Charleroi Gent Hasselt Leuven Liège

Liège Science Park Rue du Bois Saint-Jean 12 BE-4102 Seraing tél. : +32 4 361 87 00 fax : +32 4 361 87 02 info@sirris.be www.sirris.be

Nanotechnologies and their applications
Article 3

F. Monfort-Windels, J. Lecomte

January 2008- V. 2

Toute représentation ou reproduction, intégrale ou partielle, faite sans le consentement de l’auteur, ou de ses ayants droit, ou ayants cause, est illicite et constituerait une contrefaçon sanctionnée.

Table of contents
Table of contents ..............................................................................................21 Introduction ...........................................................................................................5 Nanos and autos: a running business! .........................................................7

Introduction
The articles gathered in this booklet have been published in the series “Growing with nanos!” in the Belgian magazine “PME/KMO. They are reproduced here with the kind agreement of the editor and the authors. Under the “Eureka” label, the European program MINATUSE (Micro and Nano technology Use by SMEs) aims to facilitate the integration of micro- and nanotechnologies within SMEs and to improve their participation in European projects by creating a network of assistance and information. The consortium is made up of 10 core partners, from 7 different European countries, assisted by 10 to 12 satellite members, creating a network of important European research centres active in nano- and micro technologies, and other organizations specialized in technology transfers and promotion of technological innovation. The coordinator of this project is IMEC (Belgium). The project has started in 2005 for a duration of 6 years. If you want to contact the MINATUSE members, to be informed or assisted, you can find here below the contact details of the core partners.

IMEC, Christophe Bruynseraede, christophe.bruynseraede@imec.be, tel +32 (0)16 28 13 43, www.imec.be InnovaTech, Stéphane Gualandris, stephane.gualandris@innovatech.be, tel +32 (0)71 91 98 66, www.innovatech.be Sirris, Jacky Lecomte, jacky.lecomte@sirris.be, tel +32 (0)4 361 87 65, www.sirris.be VITO, Annick Vanhulsel, annick.vanhulsel@vito.be, tel +32 (0)14 33 56 19, www.vito.be . . . . . .

www.minatuse.org

Nanos and autos: a running business!
F. Monfort-Windels Sirris

The automotive industry is an important sector, pulling forward the nanotechnologies, searching for cost and weight reduction, but also increasing performances. Following Frost & Sullivan, if the estimated global market for nanos in the automotive sector was around €932 million in 2004, it should reach 5.5 billion in 2015. The needs are not only to improve existing products like surface coatings but also to implement innovations with high industrial impact like new sensors or new energy sources. Few products based on nanotechnologies are already available at a commercial scale. Therefore their price remains very high compared with conventional solutions. The reduction of the costs should open new opportunities.

Nanotechnologies market in the automotive sector in 2015

Additives and Fuel cells Catalysts for and H2 storage fuels 1% Tyres 4% Paintings and 23% Coatings 42%

Light structures 26%

Sensors 4%

Source : Frost & Sullivan

It is not possible to make an exhaustive list of all the car components that will benefit from the contribution of nanotechnologies. Some of them are detailed in this article.

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Tyres
The first application – historically and in production volume- is the production of carbon black for the tyres. Appeared in the early 80s, this application represents today 95% of the nanos market in the automotive sector. This percentage in volume should not change significantly in the coming years. More recently, research programs have been conducted to replace carbon black by silica nano-particles. This solution reduces the resistance against rolling, and therefore the fuel consumption.

Carbon Black - Cabot Corporation

Chassis and bodywork
The field of light structures is about to exceed in value the tyres market. The need to lighten the vehicles is still urgent, with the aim of reducing the fuel consumption and the emission of exhaust fumes. Nanotechnologies will give rise to lighter and more resistant materials, either thanks to the incorporation of nanoparticles, or by the control of the structure at nanoscale. For the same application, it is therefore possible to reach the same mechanical resistance with less material and so a lighter weight, or with a lighter material with enhanced performances. Polymers reinforced with nanoclays are playing here an important role. A small amount of particles (2-5% is enough to obtain a significant improvement of the properties, like resistance, elasticity or dimensional stability, as well as specific properties like fire resistance for interior parts, or weather resistance for outer parts. General Motors did show the way in 2002 with running boards for the Safari and Astro models. This part was 8% lighter. The company continued to develop new products, like loading floors for the Hummer H2 truck, made out of polypropylene with nano-particles. Süd-Chemie has developed a ventilation grid with a nanocomposite alloy for VW and Audi. New developments are running for other components: doors stiles, dashboards, air bag covers, air filters,…

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Nanocomposites for the loading floor of the Hummer H2 2005 - General Motors

Plastic bodywork parts will undergo electrostatic painting together with metallic parts. For this, conducting polymers are obtained by the addition of carbon nanotubes. Many vehicles are already equipped with fuel tanks made in nylon loaded with carbon nanotubes, to protect them from static electricity. Magnesium is a very interesting material for the automotive sector. It is 30% lighter than aluminum and 80% lighter than steel. Its use is growing because it has an excellent ratio resistance/weight. However, it has 2 weak points: low resistance at high temperatures, and corrosion sensitivity. The control of the structure at nanoscale, or the set up of nanocomposite coatings, could solve those problems.

Engines and transmission.
In this field, the objectives are to improve the thermal efficiency and the mechanical performances while reducing the emissions (and, of course, as usual, the cost). Nanomaterials will be present in the internal structures of the engines, for instance, as nanoceramics coatings offering good wear resistance and temperature resistance in the cylinders, pistons, bearings… Nanocrystalline materials, characterized by an important ratio between the grain boundaries and the number of grains, have higher mechanical and thermal resistances. Nanostructured ceramics (zircon, alumina) or nanoreinforced ceramics (alumina + silicon nitride) are extensively studied for engine jacketing. They are more ductile and easy to form, while still hard and resistant. Nanocrystalline ceramics like Si3N4 or SiC are already used in ball bearings and valve springs.

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Ceramics nanopowders for more efficient coatings - Sirris

Tungsten and titanium boride-based nanopowders, hard and wear resistant, may increase the life time of ignition plugs and allow a more complete fuel combustion. Nanomaterials appear also in the lubricants, refrigerating or suspension fluids. Lubricants based on nanospheres reduce significantly the friction between mobile parts and minimize their wear. They improve the overall performances of the systems and reduce the maintenance costs.

Synthesis lubricants made with inorganic and spherical nanoparticles. - Apnano Materials

Many research projects are developing refrigerating fluids based on suspensions of nanoparticles in a liquid agent. The fluid conductivity is linked to the ratio surface/volume of the particles, so the heat transfer by nanofluids is more efficient. Moreover, small particles stay more easily in suspension than bigger ones

Paints and Coatings
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Paints and coatings market has been using nanoparticles for a long time. This sector will stay the most important in value for nanos in the coming 10 years. The first application is the scratch resistant paint. One layer of nanomaterials has the same efficiency than 3 layers of classical coating.

On the left: bodywork with a classical paint. On the right: scratch resistant paint with nanoparticles(nanobyk) – Byk-Chemie

Nanomaterials prospects are interesting in the field of functional surfaces, like the selfcleaning surfaces, with lotus effect. Nanos are found in materials for the improvement of the perceived quality and comfort, in coatings with sensorial, antistatic, isothermal, hydrophilic, hydrophobic, antibacterial functions, in iridescent coatings, electrochromatic or thermochromatic glazing, antiblooming windscreens, …

Hydrophobic surfaces - BASF

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The nanostructure of butterfly wings: a model for bodywork paints with visual effects - BASF

Electrical and electronic equipment
Automotive industry is an extensive user of sensors and miniaturized systems (MEMS). Two applications are already well known: the airbags accelerometer and the pressure sensor for air inlets. This market will be driven by nanotechnologies, even if today those systems are still expensive. Sensors and electronic devices allow a better man/machine interface, an improvement in wireless technologies, a more flexible ergonomics (adjustable seats), a better control of the tyres pressure… This market is still embryonic. Other projects deal with night vision, exhaust systems, interactive glazing,… The NEMS (nano-mechanical systems) shouldn’t appear before 2015. New LED diodes based on nanomaterials (quantum dots) will change radically the car lighting systems. The manufacturers are interested in sparing energy, increasing robustness lifetime, space and design flexibility offered by those products.

Energy
Energy generation and storage problems will also find solutions in the nanoworld : fuel cells, hydrogen storage, batteries, catalysts, fuel additives… The reduction of energy consumption and of gas emissions is a strong motivation for R&D. In this field, the major users of nanos will be the catalysts and electrodes for fuel cells.

Nanocubes for hydrogen storage - BASF

Thanks to their strong chemical reactivity, nanomaterials could help to reduce the amount of very expensive metals, like platinum, used in the catalysts. They are more than 500 times cheaper! On the other hand, they are active in a wide range of temperatures (-4 to
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500 °C), and therefore are efficient in all climatic circumstances, while the “classical” catalysts work efficiently around 125°C, and take a long time to reach those temperatures, mainly when the weather is cold. Adding additives in fuels catalyzes the combustion reactions in situ, improving their efficiency and reducing the harmful emissions. Very reactive, the nanoparticles stay in suspension while the classical particles sink: therefore they are more efficient.

The future
While more and more research programs are launched in nanotechnologies, new functions and new products should appear in the coming years. The development speed is still unknown, because the investment costs are high, the awareness is low, and the risks of nanomaterials for health and environment are not yet quantified. The implementation of nanos in the automotive industry is still slow, waiting for the results of the ongoing research programs.

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