...Chem 130 There will be no homework assigned this week. Use the time to study for the Exam on Fri. This Fri we will continue coverage of Nomenclature (text Chapt 5). Notes for Exam 1 Sept 28, 2015 Exam will be closed book – no books or notes will be permitted; calculators are permitted but must not connect to the internet or to outside sources of information. A periodic table with atomic numbers and atomic masses will be provided. There will be 26 questions: most multiple choice but some short answer and some calculations. You will be required to know the material and how to apply that knowledge. You will be expected to know basic conversion factors (grams –pounds, cm – in., ft – in., temp conversion equations, meanings of prefixes: milli-, centi-, kilo-, mega-, etc, but not the rarer ones). Other required conversion info will be provided (specific heats, etc.). No nomenclature on this exam. Topics and concepts to be covered: (Textbook: Chapt 1, 2, 3, 4, 10(pp288-302), 11.) Scientific method Significant figures, calculations, and scientific notation Unit conversions – temp., mass, length, volume, area, time Density; calculation of and uses of Physical and Chemical properties Physical and Chemical changes Qualitative vs quantitative observations and measurements Conservation of mass and energy Heat/temperature relationships and conversions including temp increases/decreases; heat absorbed/ released; specific heat computations; phase changes Atomic theory/atomic...
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...i50 Ann Rheum Dis 2000;59(suppl I):i50–i53 The pre-ligand binding assembly domain: a potential target of inhibition of tumour necrosis factor receptor function Francis Ka-Ming Chan Building 10, Room 11N311, Laboratory of Immunology, National Institute of Allergy and Infectious Diseases, National Institutes of Health, Bethesda, MD 20892–1892, USA Correspondence to: Dr Chan (fchan@nih.gov) Abstract Signalling by the tumour necrosis factor receptors (TNFR) is thought to be mediated by the binding of the trimeric ligand TNF to three monomeric subunits of the receptor. This ligand induced trimerisation model of TNFR signalling is mainly supported by crystallographic data of the p60 TNFR-1 and TNF complex in which the trimeric ligand interdigitates between the individual receptor chains and prevents the receptor subunits from interacting with each other. Recently, a domain NH2terminal to the ligand binding domain in the extracellular region of p60 TNFR-1, p80 TNFR-2 and Fas was identified that mediates receptor self association before ligand binding. This pre-ligand binding assembly domain or PLAD is critical for assembly of functional receptor complexes on the cell surface and may provide a potential target in the design of future novel therapeutics against diseases mediated by members of the TNFR family of receptors. (Ann Rheum Dis 2000;59(suppl I):i50–i53) Tumour necrosis factor (TNF) is a cytokine that plays an important regulatory part in both healthy and diseased...
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...Hunter College, CUNY Chem104LC Spring 2015 General Chemistry 2: Spring 2015 Section 01: Tu/Fr, 9:10am - 11:00am Section 02: Sa, 10:10am – 12:00pm Instructors: Sec 01: Nadya Kobko, PhD (Room 1320HN) Sec 02: Ravichandra Bachu, PhD (Room TBA) Email: nkobko@hunter.cuny.edu Email: rbachu@hunter.cuny.edu Office Hours: We 4 to 7 pm (or by appt.) Office Hours: TBA (1403HN, Sa) Goal of the course: This is the second semester of a 2-semester general chemistry sequence that you began in Chem 102 last semester. In Chem 104 we will cover the topics of kinetics, equilibrium, acids and bases, buffers, complex ions, thermodynamics, electrochemistry and nuclear chemistry. Chem 104 is a demanding course (more so than Chem 102) and to achieve success in this course you will need to organize large quantities of information in coherent ways so that you are able to recall and apply your knowledge. In addition you will have to learn to organize your time efficiently. And the mathematics is more demanding than in Chem 102! This semester general chemistry is run using a flipped classroom model. In this model you will watch videos and complete online homework at home and then come to class to complete workshop assignments (during your recitation section) and participate in peer-learning activities using an iClicker (during lecture every Friday). On Tuesdays during lecture we will stream the class videos for the week. This class is an optional component of the course. You should plan to spend at least...
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...Volume 38 Number 5 May 2014 Pages 1811–2146 NJC New Journal of Chemistry www.rsc.org/njc A journal for new directions in chemistry Themed issue: Advanced complex inorganic nanomaterials ISSN 1144-0546 PERSPECTIVE Pascal Van Der Voort et al. Vanadium metal–organic frameworks: structures and applications NJC PERSPECTIVE Published on 04 November 2013. Downloaded by American University of Beirut on 07/11/2014 07:39:04. View Article Online View Journal | View Issue Cite this: New J. Chem., 2014, 38, 1853 Vanadium metal–organic frameworks: structures and applications Pascal Van Der Voort,*a Karen Leus,a Ying-Ya Liu,a Matthias Vandichel,b Veronique Van Speybroeck,b Michel Waroquierb and Shyam Biswasa This perspective review paper describes the V-containing metal–organic frameworks that have been developed since the first systematic reports on MOFs almost 15 years ago. These hybrid crystalline materials, containing V(III) or V(IV) as metal nodes, show interesting behavior in oxidation catalysis and gas sorption. A significant amount of papers has appeared on the use of these structures in gas (hydrocarbon, CO2) separation. Promising future research and development of V-MOFs is suggested. Received (in Montpellier, France) 20th September 2013, Accepted 1st November 2013 DOI: 10.1039/c3nj01130e www.rsc.org/njc Introduction While MOFs based on divalent metals (Zn2+, Cu2+) have received much attention in the literature, fewer papers have appeared on...
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...SN2 vs. E2 SN2 and E2 reactions share a number of similarities. Both require good leaving groups, and both mechanisms are concerted. SN2 reactions require a good nucleophile and E2 reactions require a strong base. However, a good nucleophile is often a strong base. Since the two reactions share many of the same conditions, they often compete with each other. The outcome of the competition is determined by three factors: the presence of antiperiplanar β -hydrogens, the degree of α and β branching, and the nucleophilicity vs. basicity of the reactant species. In order for an E2 elimination to occur, there must be antiperiplanar β -hydrogens to eliminate. If there are none, the SN2 reaction will dominate. On the same token, the SN2 nucleophile needs a free path to the σ * C-LG antibond. α and β branching block this path and reduce the proportion of SN2 relative to E2 . E2 occurs even with extensive branching because it relies on the β -hydrogens, which are much more accessible than the σ * C-LG antibond. The identity of the nucleophile or base also determines which mechanism is favored. E2 reactions require strong bases. SN2 reactions require good nucleophiles. Therefore a good nucleophile that is a weak base will favor SN2 while a weak nucleophile that is a strong base will favor E2. Bulky nucleophiles have a hard time getting to the α-carbon, and thus increase the proportion of E2 to SN2. Polar, aprotic solvents increase nucleophilicity, and thus increase the rate of SN2. SN2 ...
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...Minireviews Electronic Materials M. Leskelä and M. Ritala Atomic Layer Deposition Chemistry: Recent Developments and Future Challenges** Markku Leskelä* and Mikko Ritala Keywords: atomic layer deposition · microelectronics · nitrides · oxides · thin films ew materials, namely high-k (high-permittivity) dielectrics to replace SiO2, Cu to replace Al, and barrier materials for Cu, are revolutionizing modern integrated circuits. These materials must be deposited as very thin films on structured surfaces. The self-limiting growth mechanism characteristic to atomic layer deposition (ALD) facilitates the control of film thickness at the atomic level and allows deposition on large and complex surfaces. These features make ALD a very promising technique for future integrated circuits. Recent ALD research has mainly focused on materials required in microelectronics. Chemistry, in particular the selection of suitable precursor combinations, is the key issue in ALD; many interesting results have been obtained by smart chemistry. ALD is also likely to find applications in other areas, such as magnetic recording heads, optics, demanding protective coatings, and micro-electromechanical systems, provided that cost-effective processes can be found for the materials required. N 1. Introduction Atomic layer deposition (ALD) has recently received much interest as a potential deposition method for advanced thin-film structures. However, ALD had already been developed and introduced...
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...1 1 Fundamentals of Semiconductor Electrochemistry and Photoelectrochemistry Krishnan Rajeshwar The University of Texas at Arlington, Arlington, Texas 1.1 1.2 1.3 1.3.1 1.3.2 1.3.3 1.3.4 1.4 1.4.1 1.4.2 1.4.3 1.5 1.5.1 1.5.2 1.5.3 1.5.4 1.5.5 1.6 1.7 1.7.1 1.7.2 1.7.3 1.7.4 1.7.5 Introduction and Scope . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Electron Energy Levels in Semiconductors and Energy Band Model . The Semiconductor–Electrolyte Interface at Equilibrium . . . . . . . . The Equilibration Process . . . . . . . . . . . . . . . . . . . . . . . . . . . . . The Depletion Layer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Mapping of the Semiconductor Band-edge Positions Relative to Solution Redox Levels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Surface States and Other Complications . . . . . . . . . . . . . . . . . . . Charge Transfer Processes in the Dark . . . . . . . . . . . . . . . . . . . . Current-potential Behavior . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dark Processes Mediated by Surface States or by Space Charge Layer Recombination . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Rate-limiting Steps in Charge Transfer Processes in the Dark . . . . . Light Absorption by the Semiconductor Electrode and Carrier Collection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Light Absorption...
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...Computational Condensed Matter 4 (2015) 32e39 Contents lists available at ScienceDirect Computational Condensed Matter journal homepage: http://ees.elsevier.com/cocom/default.asp Regular article Putting DFT to the trial: First principles pressure dependent analysis on optical properties of cubic perovskite SrZrO3 Ghazanfar Nazir a, b, *, Afaq Ahmad b, Muhammad Farooq Khan a, Saad Tariq b a b Department of Physics and Graphene Research Institute, Sejong University, Seoul 143-747, South Korea Centre of Excellence in Solid State Physics, University of the Punjab, Lahore, Pakistan a r t i c l e i n f o a b s t r a c t Article history: Received 8 July 2015 Received in revised form 21 July 2015 Accepted 27 July 2015 Available online 31 July 2015 Here we report optical properties for cubic phase Strontium Zirconate (SrZrO3) at different pressure values (0, 40, 100, 250 and 350) GPa under density functional theory (DFT) using Perdew-Becke-Johnson (PBE-GGA) as exchange-correlation functional. In this article we first time report all the optical properties for SrZrO3. The real and imaginary dielectric functions has investigated along with reflectivity, energy loss function, optical absorption coefficient, optical conductivity, refractive index and extinction coefficient under hydrostatic pressure. We demonstrated the indirect and direct bandgap behavior of SrZrO3 at (0) GPa and (40, 100, 250 and 350) GPa respectively. In addition, static dielectric...
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...Course Hero has millions of student submitted documents similar to the one below including study guides, practice problems, reference materials, practice exams, textbook help and tutor support. 4 Chapter PLANNING BUSINESS MESSAGES Multiple Choice 1. The three primary steps involved in preparing a business message are a. planning, writing, and completing. b. informing, persuading, and collaborating. c. defining the purpose, the main idea, and the topic. d. satisfying the audience's informational, motivational, and practical needs. ANSWER: a; DIFFICULTY: easy; PAGE: 90; TYPE: concept 2. In developing business messages, the stage during which you step back to see whether you have expressed your ideas clearly is the a. planning stage. b. writing stage. c. completing stage. d. feedback stage. ANSWER: c; DIFFICULTY: moderate; PAGE: 91; TYPE: concept 3. In preparing business messages, you should devote about ______ percent of your time to planning. a. 10 b. 20 c. 50 d. 70 ANSWER: c; DIFFICULTY: moderate; PAGE: 91; TYPE: concept 4. Which of the following is not a general purpose common to business communication? a. To inform b. To persuade c. To negotiate d. To collaborate ANSWER: c; DIFFICULTY: moderate; PAGE: 92; TYPE: concept 5. An example of a specific purpose for a business message would be a. to impart information to the audience. b. to inform employees about the new vacation policy. c. to persuade readers to take an action. d. to obtain audience participation and collaboration...
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...VINCENNES UNIVERSITY CATALOG Vol. LXIX August, 2010 No. 61 A COMPREHENSIVE TWO-YEAR COLLEGE OFFERING ASSOCIATE DEGREES IN THE LIBERAL ARTS, SCIENCES, EDUCATION, ENGINEERING, AND TECHNOLOGY AND OFFERING BACCALAUREATE DEGREES IN SPECIALIZED AREAS Accreditation The North Central Association of Colleges and Schools 30 North LaSalle Street, Suite 2400, Chicago, IL 60602 (312) 263-0456 www.ncacihe.org FAX 312-263-7462 Accreditation Review Council on Education in Surgical Technology and Surgical Assisting American Bar Association American Board of Funeral Service Education American Health Information Management Association Association of Collegiate Business Schools and Programs Commission on Accreditation of Allied Health Educational Programs Commission on Accreditation in Physical Therapy Education Federal Aviation Administration Higher Education Coordinating Board of the State of Washington Indiana State Board of Nursing Joint Review Committee on Education In Radiologic Technology National Alliance of Concurrent Enrollment Partnerships National Association of Schools of Art and Design National Association of Schools of Theatre National League for Nursing Accrediting Commission Printing Industries of America, Inc. Approved for Veterans Membership The American Association of Community Colleges Aviation Technician Education Council The Council of North Central Two Year Colleges The Higher Education Transfer Alliance The National Academic Advising Association The North Central Association...
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...2014-2015 Undergraduate Academic Calendar and Course Catalogue Published June 2014 The information contained within this document was accurate at the time of publication indicated above and is subject to change. Please consult your faculty or the Registrar’s office if you require clarification regarding the contents of this document. Note: Program map information located in the faculty sections of this document are relevant to students beginning their studies in 2014-2015, students commencing their UOIT studies during a different academic year should consult their faculty to ensure they are following the correct program map. i Message from President Tim McTiernan I am delighted to welcome you to the University of Ontario Institute of Technology (UOIT), one of Canada’s most modern and dynamic university communities. We are a university that lives by three words: challenge, innovate and connect. You have chosen a university known for how it helps students meet the challenges of the future. We have created a leading-edge, technology-enriched learning environment. We have invested in state-of-the-art research and teaching facilities. We have developed industry-ready programs that align with the university’s visionary research portfolio. UOIT is known for its innovative approaches to learning. In many cases, our undergraduate and graduate students are working alongside their professors on research projects and gaining valuable hands-on learning, which we believe is integral...
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...source for information on the College’s policies, programmes and services. Programme information in this catalogue is effective from September 2010. Students who commenced studies at the College prior to this date, are to be guided by programme requirements as stipulated by the relevant department. Updates on the schedule of classes and changes in academic policies, degree requirements, fees, new course offerings, and other information will be issued by the Office of the Registrar. Students are advised to consult with their departmental academic advisors at least once per semester, regarding their course of study. The policies, rules and regulations of the College are informed by the laws of the Republic of Trinidad and Tobago. iii Table of Contents PG 9 PG 9 PG 10 PG 11 PG 11 PG 12 PG 12 PG 13 PG 14 PG 14 PG 14 PG 14 PG 15 PG 17 PG 18 PG 20 PG 20 PG 20 PG 21 PG 22 PG 22 PG 22 PG 23 PG 23 PG 23 PG 23 PG 24 PG 24 PG 24 PG 24 PG 25 PG 25 PG 25 PG 26 PG 26 PG 26 PG 26 PG 26 PG 26 PG 27 PG 27 PG 27 PG 27 PG 27 PG 27 PG 28 PG 28 PG 28 PG 28 PG 28 PG 33 PG 37 Vision Mission President’s Welcome Institutional Profile Management Structure Registered Status and Accreditation Candidacy Commitment to Quality and Continuous Improvement Core Values General Information Equal Opportunity Disability Right to Privacy Campus Safety and Security How to Use this Catalogue List of Programmes Admissions Four-tiered Admissions Process Prior Learning and Assessment (PLA) How to Apply...
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...During the initial planning and design process construction and operational requirements of a commercial airport are established. The requirements are governed by the FAA under airport certification requirements identified in 14 CFR 139. Security systems, methods, and procedures within the construction and operational process are the obligation of TSA. The Federal Security Director (FSD) is the designated TSA official that approves the required Airport Security Program (ASP) document, the document identifies how the airport will meet security requirements. The FSD and local FAA Airports Division officials should be consulted during all phases of the project. Airport operators must integrate a Safety Management System process into their overall plan in accordance with FAA rules. Airports must establish hazard reporting systems, a risk assessment process, and a risk mitigation and assurance process with the participation of airport management. The best way to implement security in a facility is through advance planning and continuous monitoring throughout the project. Selecting, constructing, or modifying a facility without considering security for the general public, the facility, passengers, and airport and air carrier personnel can result in costly modifications. All physical security upgrades should be based on applicable Federal, State, and local laws, regulations, and policies to ensure the protection of all persons and assets (including information systems and...
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...Chem Notes Unit 1: Quantitative Chemistry, Measurement and Data Processing Unit Conversions: dm3 (decimeter^3) = L (liters) cm3 (centimeter^3) = mL (milliliters) 0 ° C (degrees celsius) = 273.15 K (Kelvin) convert Celsius into Kelvin by adding 273.15 to the current value The difference between Accuracy and Precision: Accuracy → difference between average of measured values and true value Precision → the reproducibility of the measurements, how close they are to eachother Types of Error: Systematic Error → fundamental flaws in equipment, observer. Leads to values all higher or lower than actual value. High precision, low accuracy. Random Error → uncertainty in measurement devices. Leads to random variation in values. Always occurs and can generally not be improved. Precise measurements have low random error. Accurate measurements have low systematic error and generally low random error. Uncertainties: Graduated/Analog Device → ±1/2 of the smallest increment on the device. Digital Device → ±1 on the last digit the device records (it estimates for you.) Exact Values → No uncertainty. For all uncertainties the recorded value MUST be to the same decimal place as the uncertainty. Change your final answer's significant digits if necessary. Uncertainties should be rounded to ONE digit. Propagation of Uncertainties: Addition and Subtraction → Add uncertainties. Multiplication and Division → Calculate Relative Uncertainty by dividing...
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...Quantum Theory Electrons behave like particles in some experiments, and like waves in others. The electron's 'wave/particle duality' has no real analogy in the everyday world. The quantum theory that describes the behavior of electrons is a cornerstone in modern chemistry. Quantum theory can be used to explain why atoms are stable, why things have the color they do, why the periodic table has the structure it does, why chemical bonds form, and why different elements combine in different ratios with each other. Light and electrons both behave quantum mechanically. To understand the experimental basis for the quantum theory, we have to begin our discussion with light. Waves * Waves are an oscillation that moves outward from a disturbance (ripples moving away from a pebble dropped into a pond) Properties of waves | property | definition | symbol | SI units | velocity | distance traveled per second | c | m/s | amplitude | peak height above midline | A | varies with type of wave | wavelength | peak-to-peak distance | | m | frequency | number of peaks passing by per second | | s-1 (called Hertz) | | * relationship between frequency and wavelength * distance per cycle × cycles per second = distance per second = c * examples * The speed of sound in air is 330 m/s. Humans can hear sounds with wavelengths between 17 m and 17 mm. What is the highest sound frequency that is audible? * interference * constructive interference:...
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