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Photoelectric Effect: Solar Energy

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The Photoelectric Effect: How Solar Electricity is Generated

Solar energy is an evolving source of power that gradually is becoming more popular to be used as a viable replacement for (or for at least some) of the commonly used power sources around the world today, such as coal, natural gas, and nuclear power. About 67% of electricity generated in the United States comes from fossil fuels, and 39% of that comes from coal plants. Because many scientists of The Industrial Revolution strongly believed that fossil fuels such as coal would eventually run out, some of them looked for different ways to generate energy. Thus, dating far back to the early 1800s, power generation through the photoelectric and photovoltaic effects were discovered. Solar energy is generated by solar panels, which are composed of individual solar cells (or photovoltaic cells) that absorb light from the sun - the light absorbed is then turned into electricity. The absorption of light can be attributed to two processes, one being the photoelectric effect, and the other the photovoltaic effect. While these sound similar, they are closely related, but are different processes. Understanding and using both of them together is extremely important in the process of generation of electricity through solar cells. The photoelectric effect was observed by Heinrich Hertz in 1887 while experimenting on work involved with radio waves. He found that when ultraviolet light was shone upon two metal electrodes conducting a current to create sparks, the light changed the voltage at which the electric sparks were created. Why did this happen? Well, electromagnetic radiation is made up of particles called photons, which upon contact with a metal surface, can cause an electron to emit. However, not all waves of electromagnetic radiation will cause an electron to emit from any metal as there is a minimum frequency that electromagnetic radiation must reach, or surpass, in order for this to happen. This is known as the “cutoff frequency” or “threshold frequency”. This frequency is used to determine something known as the “work function”, which is the amount of energy holding an electron to the surface. Because of the cutoff frequency and work function in the photoelectric effect, not all light can be absorbed into solar panels and special materials must be used in the building of photovoltaic cells to maximize generation of electricity. The photovoltaic effect in simple terms is light striking two dissimilar materials (typically metals and crystals in the case of solar cells) and generating electrical voltage from the electrons that are emitted. In a solar cell, a semiconductor (typically silicon) is specially treated to create an electrical field, one side being positive, the other being negative. When light strikes the cell, electrons are knocked loose from the atoms of the semiconductor. On the solar cell there are metal contact grids on either side of the semiconductor, these grids capture the electrons into an electrical current and thus generating electricity as long as light is shining onto the cell. Many of these singular cells are linked together into larger modules, and the modules are linked into an array, giving you a solar panel. Now we know how sunlight is converted into electricity in the simplest terms. But lets go back to the photoelectric effect. Do you remember what the cutoff frequency is? It makes a big difference to where solar cells can be placed, how they can be used, and how efficient they are. Because there are different frequencies of light (high powered photons to low powered photons), that cause electrons to emit from a metal, electrons may not be freed from a metal at all unless the power of the photon is equal or greater to than the “band gap” of the cell material. For example, a specific solar cell material will be limited to absorbing only a high powered part of the sun's spectrum of light, and low powered photons will not be used. This means that creating a high efficiency solar cell requires layering different cell materials into a “multijunction” cell that absorbs different frequencies of light, thus generating more electricity. For another example, solar powered calculators use solar strips engineered to absorb the low powered photon frequencies of indoor lighting to generate power. After all, calculators aren't typically used outdoors in the sun. Solar generated electricity is truly an amazing discovery, the photoelectric and photovoltaic effects are phenomenons in their own right. The fact that power can be generated from an invention by simply being in the presence of light is outstanding. From solar power's early observation almost 200 years ago and its continual evolving into what it is now, is one of the great story's of science, and while solar power (for the time being) isn't our main source of energy, who knows what the future holds? As these processes are refined and perfected, and the world's need for renewable energy increases, the use of solar energy will continue to expand.

http://pveducation.org/pvcdrom/pn-junction/band-gap http://www.britannica.com/EBchecked/topic/458271/photovoltaic-effect http://www.princeton.edu/~achaney/tmve/wiki100k/docs/Work_function.html http://www.britannica.com/EBchecked/topic/457841/photoelectric-effect/5705/Discovery-and-early-work http://science.nasa.gov/science-news/science-at-nasa/2002/solarcells/ http://www.einsteinyear.org/facts/photoelectric_effect/ http://www.physics.org/article-questions.asp?id=51 http://chemistry.about.com/od/electronicstructure/a/photoelectric-effect.htm http://www.eia.gov/tools/faqs/faq.cfm?id=427&t=3

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