...Volume 38 Number 5 May 2014 Pages 1811–2146 NJC New Journal of Chemistry www.rsc.org/njc A journal for new directions in chemistry Themed issue: Advanced complex inorganic nanomaterials ISSN 1144-0546 PERSPECTIVE Pascal Van Der Voort et al. Vanadium metal–organic frameworks: structures and applications NJC PERSPECTIVE Published on 04 November 2013. Downloaded by American University of Beirut on 07/11/2014 07:39:04. View Article Online View Journal | View Issue Cite this: New J. Chem., 2014, 38, 1853 Vanadium metal–organic frameworks: structures and applications Pascal Van Der Voort,*a Karen Leus,a Ying-Ya Liu,a Matthias Vandichel,b Veronique Van Speybroeck,b Michel Waroquierb and Shyam Biswasa This perspective review paper describes the V-containing metal–organic frameworks that have been developed since the first systematic reports on MOFs almost 15 years ago. These hybrid crystalline materials, containing V(III) or V(IV) as metal nodes, show interesting behavior in oxidation catalysis and gas sorption. A significant amount of papers has appeared on the use of these structures in gas (hydrocarbon, CO2) separation. Promising future research and development of V-MOFs is suggested. Received (in Montpellier, France) 20th September 2013, Accepted 1st November 2013 DOI: 10.1039/c3nj01130e www.rsc.org/njc Introduction While MOFs based on divalent metals (Zn2+, Cu2+) have received much attention in the literature, fewer papers have appeared on...
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...View Online / Journal Homepage / Table of Contents for this issue Catalysis Science & Technology Cite this: Catal. Sci. Technol., 2012, 2, 2025–2036 www.rsc.org/catalysis Dynamic Article Links MINIREVIEW Advances in conversion of hemicellulosic biomass to furfural and upgrading to biofuels Saikat Dutta, Sudipta De, Basudeb Saha* and Md. Imteyaz Alam Downloaded on 15 September 2012 Published on 01 June 2012 on http://pubs.rsc.org | doi:10.1039/C2CY20235B Received 14th April 2012, Accepted 28th May 2012 DOI: 10.1039/c2cy20235b Recent approaches to furfural synthesis from hemicellulosic biomass and pentose sugars with both homogeneous and solid acidic catalysts have been summarized by addressing the associated sustainability issues. The features of deconstruction of hemicellulosic biomass by acid hydrolysis to produce pentose sugar feedstock for furfural have been discussed in brief. Several strategies including solvent extraction in a biphasic process, application of surface functionalized materials such as acidic resins, mesoporous solids and mechanistic insight in limited cases are discussed. The present status of the promising furfural platform in producing second generation biofuels (furanics and hydrocarbon) is reviewed. The performances of each catalytic system are assessed in terms of intrinsic reactivity and selectivity toward furfural production. Overall, this minireview attempts to highlight the scope of further developments for a sustainable furfural...
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...Fachhochschule Bonn-Rhein-Sieg University of Applied Sciences Fachbereich Angewandte Naturwissenschaften Department of Applied Sciences Laboratory Course in Instrumental Analysis WS 2014 - 2015 Instructor: Tutors: Dr. G. Holl Dipl. Ing (FH) Olav Schweiger Dipl. Chem Michel Bergs Experiment: UV/VIS spectroscopy – Principles Note: Please use the gaps in this instruction for your answers, if needed use the back of the sheet. Do not use any extra sheets of paper. Handwriting is OK you don’t need a computer for your protocol. Instrumental Analysis Lab UV/VIS spectroscopy - Principles 1.1. Basic Principles - What is a UV-visible Spectrum? Introduction A spectrum is a graphical representation of the amount of light absorbed or transmitted by matter as a function of wavelength. A UV-visible spectrophotometer measures absorbance or transmittance from the UV range to which the human eye is not sensitive to the visible wavelength range to which the human eye is sensitive. In the following experiment the spectra of a coloured and an uncoloured compound is measured. It will be demonstrated that in many cases uncoloured compounds have a UV absorbance. Reagents and Equipment O H3C Caffeine (a) Erythrosine deionized water CH3 N Two 1.0 L volumetric flasks 0.5 mL syringe or pipette Disposable glass pipettes (minimum 3) 10-mm path length quartz cell, 3 ml volume O N N N CH3 (a) ...
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...SECOND EDITION ELECTROCHEMICAL METHODS Fundamentals and Applications Allen J. Bard Larry R. Faulkner Department of Chemistry and Biochemistry University of Texas at Austin JOHN WILEY & SONS, INC. New Yorke Chichester • Weinheim Brisbane e Singapore e Toronto Acquisitions Editor David Harris Senior Production Editor Elizabeth Swain Senior Marketing Manager Charity Robey Illustration Editor Eugene Aiello This book was set in 10/12 Times Roman by University Graphics and printed and bound by Hamilton. The cover was printed by Phoenix. This book is printed on acid-free paper, oo Copyright 2001 © John Wiley & Sons, Inc. All rights reserved. No part of this publication may be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning or otherwise, except as permitted under Sections 107 or 108 of the 1976 United States Copyright Act, without either the prior written permission of the Publisher, or authorization through payment of the appropriate per-copy fee to the Copyright Clearance Center, 222 Rosewood Drive, Danvers, MA 01923, (978) 750-8400, fax (978) 750-4470. Requests to the Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc., 605 Third Avenue, New York, NY 10158-0012, (212) 850-6011, fax (212) 850-6008, E-Mail: PERMREQ@WILEY.COM. To order books or for customer service, call 1 (800)-CALL-WILEY (225-5945). Library of Congress Cataloging...
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...Classification Tests for Hydroxyl- and Carbonyl-containing Compounds Miguel, K.D., Moron, R.S.S., Pazon, A.D., Ramirez, C.V., Raquepo, T.M.R., Razon, D.N.A.Jr. 2B-PH, Group No. 6, Department of Pharmacy, Faculty of Pharmacy, University of Santo Tomas, España Boulevard, 1015 Manila, Philippines Abstract In organic chemistry it is very common to see molecules comprised mainly of a carbon backbone with functional groups attached to the chain. The functional group gives the molecule its properties, regardless of what molecule contains it.[1] Examples of functional groups are that of hydroxyl (-OH) which is usually seen in alcohols, and carbonyl (C=0) which is seen in aldehydes and ketones. In this experiment, several tests were conducted to distinguish and differentiate various sample compounds such as ethanol, n-butyl alcohol, sec-butyl alcohol, tert-butyl alcohol, benzyl alcohol, n-butyraldehyde, benzaldehyde, acetone, acetophenone, isopropyl alcohol, and acetaldehyde. The tests are the following: solubility test of alcohols in water, which gave a soluble result in ethanol, sec-butyl alcohol and tert-butyl alcohol. Next is the Lucas test, which is used to differentiate 1°, 2° & 3° alcohols. In Lucas test, tert-butyl alcohol gave an immediate turbid result; the rate of reaction was noted. Chromic Acid test (Jones Oxidation) which gave a positive result by producing a blue-green solution with the sample n-butyl alcohol, acetaldehyde, benzaldehyde, and isopropyl alcohol. 2...
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...Organic Chemistry Second Edition The INSTANT NOTES series Series Editor: B.D. Hames School of Biochemistry and Molecular Biology, University of Leeds, Leeds, UK Animal Biology 2nd edition Biochemistry 2nd edition Bioinformatics Chemistry for Biologists 2nd edition Developmental Biology Ecology 2nd edition Immunology 2nd edition Genetics 2nd edition Microbiology 2nd edition Molecular Biology 2nd edition Neuroscience Plant Biology Chemistry series Consulting Editor: Howard Stanbury Analytical Chemistry Inorganic Chemistry 2nd edition Medicinal Chemistry Organic Chemistry 2nd edition Physical Chemistry Psychology series Sub-series Editor: Hugh Wagner Dept of Psychology, University of Central Lancashire, Preston, UK Psychology Forthcoming titles Cognitive Psychology Physiological Psychology Organic Chemistry Second Edition G. L. Patrick Department of Chemistry and Chemical Engineering, Paisley University, Paisley, Scotland This edition published in the Taylor & Francis e-Library, 2005. "To purchase your own copy of this or any of Taylor & Francis or Routledge's collection of thousands of eBooks please go to www.eBookstore. tandf.co.uk.” © Garland Science/BIOS Scientific Publishers, 2004 First published 2000 Second edition published 2004 All rights reserved. No part of this book may be reproduced or transmitted, in any form or by any means, without permission. A CIP catalogue record for this book is available from the British Library. ISBN 0-203-42761-0 Master e-book...
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...1 1 Fundamentals of Semiconductor Electrochemistry and Photoelectrochemistry Krishnan Rajeshwar The University of Texas at Arlington, Arlington, Texas 1.1 1.2 1.3 1.3.1 1.3.2 1.3.3 1.3.4 1.4 1.4.1 1.4.2 1.4.3 1.5 1.5.1 1.5.2 1.5.3 1.5.4 1.5.5 1.6 1.7 1.7.1 1.7.2 1.7.3 1.7.4 1.7.5 Introduction and Scope . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Electron Energy Levels in Semiconductors and Energy Band Model . The Semiconductor–Electrolyte Interface at Equilibrium . . . . . . . . The Equilibration Process . . . . . . . . . . . . . . . . . . . . . . . . . . . . . The Depletion Layer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Mapping of the Semiconductor Band-edge Positions Relative to Solution Redox Levels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Surface States and Other Complications . . . . . . . . . . . . . . . . . . . Charge Transfer Processes in the Dark . . . . . . . . . . . . . . . . . . . . Current-potential Behavior . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dark Processes Mediated by Surface States or by Space Charge Layer Recombination . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Rate-limiting Steps in Charge Transfer Processes in the Dark . . . . . Light Absorption by the Semiconductor Electrode and Carrier Collection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Light Absorption...
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...Chemistry Modern Analytical Chemistry David Harvey DePauw University Boston Burr Ridge, IL Dubuque, IA Madison, WI New York San Francisco St. Louis Bangkok Bogotá Caracas Lisbon London Madrid Mexico City Milan New Delhi Seoul Singapore Sydney Taipei Toronto McGraw-Hill Higher Education A Division of The McGraw-Hill Companies MODERN ANALYTICAL CHEMISTRY Copyright © 2000 by The McGraw-Hill Companies, Inc. All rights reserved. Printed in the United States of America. Except as permitted under the United States Copyright Act of 1976, no part of this publication may be reproduced or distributed in any form or by any means, or stored in a data base or retrieval system, without the prior written permission of the publisher. This book is printed on acid-free paper. 1 2 3 4 5 6 7 8 9 0 KGP/KGP 0 9 8 7 6 5 4 3 2 1 0 ISBN 0–07–237547–7 Vice president and editorial director: Kevin T. Kane Publisher: James M. Smith Sponsoring editor: Kent A. Peterson Editorial assistant: Jennifer L. Bensink Developmental editor: Shirley R. Oberbroeckling Senior marketing manager: Martin J. Lange Senior project manager: Jayne Klein Production supervisor: Laura Fuller Coordinator of freelance design: Michelle D. Whitaker Senior photo research coordinator: Lori Hancock Senior supplement coordinator: Audrey A. Reiter Compositor: Shepherd, Inc. Typeface: 10/12 Minion Printer: Quebecor Printing Book Group/Kingsport Freelance cover/interior designer: Elise Lansdon Cover image: © George Diebold/The...
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...Table of Contents Partial table of contents: Carbon Compounds and Chemical Bonds. Representative Carbon Compounds. An Introduction to Organic Reactions: Acids and Bases. Alkanes and Cycloalkanes: Conformations of Molecules. Stereochemistry: Chiral Molecules. Alkenes and Alkynes I: Properties and Synthesis. Alkenes and Alkynes II: Addition Reactions. Radical Reactions. Alcohols and Ethers. Conjugated Unsaturated Systems. Aromatic Compounds. Reactions of Aromatic Compounds. Aldehydes and Ketones I: Nucleophilic Additions to the Carbonyl Group. Aldehydes and Ketones II: Aldol Reactions. Carboxylic Acids and Their Derivatives: Nucleophilic Substitution at the Acyl Carbon. Amines. Carbohydrates. Lipids. Answers to Selected Problems. Glossary. Index. Solomons/Advices ADVICES FOR STUDYING ORGANIC CHEMISTRY 1. Keep up with your studying day to day –– never let yourself get behind, or better yet, be a little ahead of your instructor. Organic chemistry is a course in which one idea almost always builds on another that has gone before. 2. Study materials in small units, and be sure that you understand each new section before you go on to the next. Because of the cumulative nature of organic chemistry, your studying will be much more effective if you take each new idea as it comes and try to understand it completely before you move onto the nest concept. 3. Work all of the in-chapter and assigned problems. 4. Write when you study. over and over again. Write the reactions, mechanisms...
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...2014-2015 Undergraduate Academic Calendar and Course Catalogue Published June 2014 The information contained within this document was accurate at the time of publication indicated above and is subject to change. Please consult your faculty or the Registrar’s office if you require clarification regarding the contents of this document. Note: Program map information located in the faculty sections of this document are relevant to students beginning their studies in 2014-2015, students commencing their UOIT studies during a different academic year should consult their faculty to ensure they are following the correct program map. i Message from President Tim McTiernan I am delighted to welcome you to the University of Ontario Institute of Technology (UOIT), one of Canada’s most modern and dynamic university communities. We are a university that lives by three words: challenge, innovate and connect. You have chosen a university known for how it helps students meet the challenges of the future. We have created a leading-edge, technology-enriched learning environment. We have invested in state-of-the-art research and teaching facilities. We have developed industry-ready programs that align with the university’s visionary research portfolio. UOIT is known for its innovative approaches to learning. In many cases, our undergraduate and graduate students are working alongside their professors on research projects and gaining valuable hands-on learning, which we believe is integral...
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...Transforming Lives Communities The Nation …One Student at a Time Disclaimer Academic programmes, requirements, courses, tuition, and fee schedules listed in this catalogue are subject to change at any time at the discretion of the Management and Board of Trustees of the College of Science, Technology and Applied Arts of Trinidad and Tobago (COSTAATT). The COSTAATT Catalogue is the authoritative source for information on the College’s policies, programmes and services. Programme information in this catalogue is effective from September 2010. Students who commenced studies at the College prior to this date, are to be guided by programme requirements as stipulated by the relevant department. Updates on the schedule of classes and changes in academic policies, degree requirements, fees, new course offerings, and other information will be issued by the Office of the Registrar. Students are advised to consult with their departmental academic advisors at least once per semester, regarding their course of study. The policies, rules and regulations of the College are informed by the laws of the Republic of Trinidad and Tobago. iii Table of Contents PG 9 PG 9 PG 10 PG 11 PG 11 PG 12 PG 12 PG 13 PG 14 PG 14 PG 14 PG 14 PG 15 PG 17 PG 18 PG 20 PG 20 PG 20 PG 21 PG 22 PG 22 PG 22 PG 23 PG 23 PG 23 PG 23 PG 24 PG 24 PG 24 PG 24 PG 25 PG 25 PG 25 PG 26 PG 26 PG 26 PG 26 PG 26 PG 26 PG 27 PG 27 PG 27 PG 27 PG 27 PG 27 PG 28 PG 28 PG 28 PG 28 PG 28 PG 33 PG 37 Vision Mission President’s...
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...STRUCTURAL ORGANIC CHEMISTRY. THE SHAPES OF MOLECULES. FUNCTIONAL GROUPS I n this chapter we first briefly review the most important types of covalent bonds encountered in organic substances and the ways in which these bonds are represented in structural formulas. Next we consider the sizes and shapes of organic molecules and how structural formulas written in two dimensions can be translated into three-dimensional models that show the relative positions of the atoms in space. We also discuss models that reflect the relative sizes of the atoms and the way in which the atoms may interfere with each other when in close quarters (steric hindrance). Then we go on to further important aspects of structure-the functional group concept and position isomerism. Our aim is to have you become more familiar with the various kinds of organic compounds and begin to see how the practicing organic chemist visualizes molecules and correlates the diverse kinds of structures that he has to deal with in his work. 2-1 STRUCTURAL FORMULAS The building block of structural organic chemistry is the tetravalent carbon atom. With few exceptions, carbon compounds can be formulated with four 2-1 Structural Fbrmulas 31 covalent bonds to each carbon, regardless of whether the combination is with carbon or some other element. The two-electron bond, which is illustrated by the carbon-hydrogen bonds in methane or ethane and the carbon-carbon bond in ethane, is called a single...
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...Killer Cover Letters & Resumes! WetFeet Insider Guide by Rosanne Lurie The WetFeet Research Methodology You hold in your hands a copy of the best-quality research available for job seekers. We have designed this Insider Guide to save you time doing your job research and to provide highly accurate information written precisely for the needs of the job-seeking public. (We also hope that you’ll enjoy reading it, because, believe it or not, the job search doesn’t have to be a pain in the neck.) Each WetFeet Insider Guide represents hundreds of hours of careful research and writing. We start with a review of the public information available. (Our writers are also experts in reading between the lines.) We augment this information with dozens of in-depth interviews of people who actually work for each company or industry we cover. And, although we keep the identity of the rank-and-file employees anonymous to encourage candor, we also interview the company’s recruiting staff extensively, to make sure that we give you, the reader, accurate information about recruiting, process, compensation, hiring targets, and so on. (WetFeet retains all editorial control of the product.) We also regularly survey our members and customers to learn about their experiences in the recruiting process. Finally, each Insider Guide goes through an editorial review and fact-checking process to make sure that the information and writing live up to our exacting standards before it goes out the door. Are...
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...COUNCIL DIRECTIVE ON AMBIENT AIR QUALITY ASSESSMENT AND MANAGEMENT WORKING GROUP ON BENZENE POSITION PAPER September 1998 COUNCIL DIRECTIVE ON AMBIENT AIR QUALITY ASSESSMENT AND MANAGEMENT WORKING GROUP ON BENZENE 1 POSITION PAPER PREFACE Scope Summary 1. INTRODUCTION 1.1 Benzene in the atmosphere 1.2 Emissions of benzene 1.3 Atmospheric chemistry and transport 1.4 Benzene ambient air concentrations 1.5 Current National Standards and Guidelines 1.6 Summary 1.7 References 2. RISK ASSESSMENT Scope 2.1. 2.2 2.3. 2.4. 2.5. 2.6 Human exposure to benzene Health Effects National and other Health-based Air Quality Guidelines Evaluation of human health risks Recommendations for developing limit values Reference 2. ASSESSMENT METHODS Scope 3.1 Introduction 3.2 Description of monitoring methods 3.3 Network design and siting criteria 3.4 Other assessment techniques: air quality modelling 3.5 Data quality objectives 3.6 Random or continuous measurements 3.7 Information on air quality to the public 3.8 Upper and lower assessment thresholds 3.9 Summary 3.10 References 2 4 ECONOMIC ANALYSIS 4.1 Introduction 4.2 Results of economic analysis 4.3 Discussion 5 DISCUSSION AND FINAL RECOMMENDATIONS 5.1 Summary of Chapters 1-4 5.2 Considerations to be taken into account in setting limit values for benzene 5.3 Options for consideration 5.4 Reviewing limit values 3 COMMISSION OF EUROPEAN COMMUNITIES Council Directive on Ambient Air Quality Assessment and Management...
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...NOAA Technical Memorandum NOS ORCA 114 Integrating Physical and Biological Studies of Recovery from the Exxon Valdez Oil Spill Case Studies of Four Sites in Prince William Sound, 1989-1994 September 1997 Seattle, Washington noaa NATIONAL OCEANIC AND ATMOSPHERIC ADMINISTRATION National Ocean Service Office of Ocean Resources Conservation and Assessment National Ocean Service National Oceanic and Atmospheric Administration U.S. Department of Commerce The Office of Ocean Resources Conservation and Assessment (ORCA) provides decisionmakers comprehensive, scientific information on characteristics of the oceans, coastal areas, and estuaries of the United States of America. The information ranges from strategic, national assessments of coastal and estuarine environmental quality to real-time information for navigation or hazardous materials spill response. Through its National Status and Trends (NS&T) Program, ORCA uses uniform techniques to monitor toxic chemical contamination of bottom-feeding fish, mussels and oysters, and sediments at about 300 locations throughout the United States. A related NS&T Program of directed research examines the relationships between contaminant exposure and indicators of biological responses in fish and shellfish. ORCA provides critical scientific support to the U.S. Coast Guard during spills of oil or hazardous materials into marine or estuarine environments. This support includes spill trajectory predictions, chemical...
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