...Massachusetts Lowell Department of Chemistry Determination of equivalence point using pH titration of Potassium Hydrogen Phalate and 0.1 N Sodium Hydroxide with phenolphthalein indicator By Lee Binks (12647892), Penny Jinks (12993456) and Hong Links 13504733) Date submitted: Sept 18th , 2013 Abstract- The experiment described elucidates the fundamental principle of potentiometric titrations and determination of equivalence point using pH titration of Potassium Hydrogen Phalate and 0.1 N Sodium Hydroxide with the use of phenolphthalein indicator. The present study revealed the equivalence point by using simple titration curve which was further confirmed by using first and second derivative plots and pKa value of the Potassium Hydrogen Phalate. Introduction- The pH meter measures the pH of a solution and provides a direct method of obtaining a titration curve which is a graph of measured pH values versus the volume of titrant added in milliliters. The equivalence point is the point at which a stoichiometrically equivalent amount of base has been added to the acid. It does not mean that pH will be necessarily 7. KHP is a monoprotic acid. The neutralization with NaOH takes place in a 1:1 ratio HOOCC6H4COOK (aq) + NaOH ( aq) ---> C6H4 ( COO)2 2- (aq) + K+ (aq) + Na+ (aq) The equivalence point occurs in the region where there is a relatively large change in pH with a relatively small change in volume on the titration curve...
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...An Oxidation-Reduction Titration: The Reaction of Fe2+ and Ce4+ LAB ADV COMP 8 From Advanced Chemistry with Vernier, Vernier Software & Technology, 2004 INTRODUCTION A titration, as you recall, is a convenient method of learning more about a solution by reacting it with a second solution of known molar concentration. There are a number of ways to measure the progress of a titration. The method used in this experiment is called a potentiometric titration, in which the electric potential of a reaction is monitored. All acid-base titrations that are measured by a pH probe are potentiometric; thus, this method is not as unusual as it may seem. You will conduct an oxidation-reduction reaction in this experiment in order to determine the amount of iron (II) ions in a solid sample of ferrous ammonium sulfate hexahydrate, (NH4)2Fe(SO4)2•6H2O. The oxidizing agent for the sample will be ammonium cerium (IV) nitrate, (NH4)2Ce(NO3)6. The net ionic equation for the reaction is shown below. Ce4+ (aq) + Fe2+ (aq) → Ce3+ (aq) + Fe3+ (aq) This experiment illustrates the electrical nature of chemical reactions, and offers practice with a process for observing and measuring an oxidation-reduction reaction. OBJECTIVES In this experiment, you will • Conduct the potentiometric titration of the reaction between ferrous ammonium sulfate hexahydrate and ammonium cerium (IV) nitrate. • Measure the potential change of the reaction. • Determine the molar concentration of iron (II) ions in...
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...important? Carboxylic acid functional groups serve many purposes they confer to the polymer the ability to interact with a variety of substances. For example The use of amino based monomers with carboxylic acid moiety is the ability to adapt the polymers for various interactions with substances such as metal ions, non-ionic proton-accepting polymers, their derivatives, and cationic polyelectrolytes. As such these polymers can serve as a way of delivering drugs to targeted zones. Furthermore by polymerizing the monomers without the need for protecting groups serves a much more significant purpose on an industrial size. By avoiding the use of protecting groups one can avoid added steps in the industrial process, as such reducing the opportunities for errors to occur and avoiding additional costs associated with the protecting groups, for example added operation costs, capital costs. Results Describe a selection of the experimental results from the three papers. Show: The results I will be discussing is the effect of solvent and CTA on polymerization. Article 1: Scheme: Figure 2: RAFT Polymerization of Acrylamide Derivatives Containing l-Phenylalanine Moiety Table 1: Effects of Temperature and Solvent on...
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...system. The heater was also turned OFF as there is no necessity for heating. 2. A final check was done to ensure that the instrument air supply was 25 psig (1.7 Barg), the overflow drain valve and the vent at tank T11 were opened. 3. Tank 12 was filled with water till its level reached the over-flow drain pipe outlet (D). 4. The main power supply switch at the Electrical Cubicle was turned ON. The control panel instrument lid up. 5. All controllers were set to Manual (Mode). The output (MV) of LIC11 was manually adjusted to about 55%. The output of TIC11 was manually adjusted to about 50%. The stem position was visually checked to ensure it is at the position of about 50%, with the positioner PP controlling. 6. Pump P12 was started and it was verified that the pump is pumping. The by-pass valve was shut and the rise of water in tank T11 was observed from the sight glass. 7. Pump P11 was started after the water level in tank T11 was about 50%. P11 was verified to be pumping through the heat exchanger by visually checked its discharge at tank T12. 8. Both TCV11 and LCV11 were manually regulated from their controllers TIC11 and FIC11 (in Manual Mode) so that the water level in tank T11 remains steady. 9. The following displays were observed. LFTR11 | LIC/FIC11 | PEN | DIGITAL | LIC | FIC | Level (LT11)Red (%) | 0 – 1000mmH/O | PV1 | | Inflow (FT12)Green (%) | 0 –...
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...COURSE OUTLINE FOR THE CURRENT SEMESTER (Final year) Note: This course outline has been adopted from the syllabus prescribed & approved by the Higher Education Commission (HEC) and Pharmacy Council of Pakistan (PCP). Alterations in this syllabus have been made by the concerned institute. The original course outline with complete syllabus details for five years, are available for free download at the HEC website. Please follow this link. http://www.hec.gov.pk/InsideHEC/Divisions/AECA/CurriculumRevision/Pages/CurriculumRevision.aspx “FIFTH PROFESSIONAL” SEMESTER IX (701) PHARMACEUTICAL CHEMISTRY - V (Medicinal Chem. - I) [Theory] Credit hours = 03 NOTE: The topics will be taught with special reference to their Pharmaceutical applications. 1). INTRODUCTION TO MEDICINAL CHEMISTRY: Chemical constitution and biological activity: (Receptor Theory, Structure Activity Relationships (SAR) and Drug Metabolism). 2). CLASSIFICATION OF DRUGS: Classification of drugs based on source, structure, site of action, mode of action. 3). DRUG DESIGNING: Discovery of lead structure (different approaches). Structural features of drugs. Drug receptor interaction, Physico chemical properties of drugs. 4). DRUG METABOLISM: Inactive, Biologically active and Chemically reactive metabolites, Phase I & II reactions. 5). STRUCTURE ACTIVITY RELATIONSHIP. 6). GENERAL PROPERTIES, CHEMISTRY (General methods of determination...
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...the author(s). Contents of the paper have not been reviewed by the Offshore Technology Conference and are subject to correction by the author(s). The material does not necessarily reflect any position of the Offshore Technology Conference, its officers, or members. Electronic reproduction, distribution, or storage of any part of this paper without the written consent of the Offshore Technology Conference is prohibited. Permission to reproduce in print is restricted to an abstract of not more than 300 words; illustrations may not be copied. The abstract mus t contain conspicuous acknowledgment of OTC copyright. Abstract Successful installation of subsea structures and equipment is critical for offshore campaigns in development of deep-water fields. This paper presents a novel approach using Fluid-Structure Interaction (FSI) to predict wave induced motions, wave loads, dynamic stresses and deformation of subsea structure and equipments in the splash zone during installation. This approach combines transient multiphase CFD simulation including dynamic mesh motion with transient nonlinear Computational Structural Dynamics including tension forces in non-linear flexible slings. This proposed approach has been successfully implemented for lowering of a subsea manifold in splash zone during installation. This paper has many potential applications, such as, installation of manifold, subsea tree, PLET/PLEM, suction pile,...
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...carried out in Schlenk tubes immersed in a thermostatted oil bath controlled to 65°C / 110°C and with a stirring rate of 300 rpm. In a typical experiment, 5 mg of cationic complex was introduced to 2g of thermostatted styrene (2 g) without solvent. After 2 h, the reaction was terminated by flushing the solution with air to decompose the catalyst. The decomposed catalyst and unreacted styrene and was removed from the reaction mixture by filtration on a fritted glass and washed it by 100 mL of methanol. The oligomers were characterized by gel permeation chromatography, GPC/SEC analysis were performed by eluting THF solutions of the polymeric samples at 30 ºC (Waters oven) in two PolyPore columns (protected by a PolyPore guard column) (Polymer Labs) mounted on a Waters 1515 isocratic HPLC pump. Detection was performed by a Waters 2414 differential refractive index detector. The THF eluent was filtered through 0.45 µm PTFE Pall membrane filters and degassed in an ultrasound bath. Solution samples were filtered through 0.20 µm PTFE GVS filters. The system was calibrated with TSK Tosoh Co. polystyrene standards. Table 3: Oligomerization styrene catalyzed by complexes C1 and...
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...dollar. However, none of these these items are of long lasting quality. That play dough is not moldable, the crayons off colored and the pencil case will break at first sign of impact. Something that is poorly made will perform as such, and that is a universal truth. With fast food restaurants popping up on every corner featuring America’s favorite - the drive-thru - this concept is applicable the evolution taking place within culinary culture. Over the years, many consumers have chosen to stray from quality to pursue the convenience of fast food, resulting in the overtaking of family farms and substantial decline in overall value. All culinary manufacturing originated within the hearts of a family farm. For all intensive purposes, these plots of sod can be seen as the starting point of this potentially cyclical evolution, mentioned previously, of the fast food industry. Traditionally, seed was laid by farmers, watered by farmers, tended to and harvested by farmers and sold by the farmers. This process was originally done with their own hands or those of their offspring and it was viewed as a sense of honor. In fact, family farms were passed down the male family line and it was the most common source of income. Obviously, their techniques evolved over time to allow for greater efficiency. Tractors and vehicular seed-setters were invented and placed into circulation. However, much to these farmer’s dismay, the technological evolution did not cease. As major corporations recognized...
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...The improper and excessive use of these drugs, especially when withdraw periods are not observed, may result in the presence of their residues in edible animal tissues, especially when withdraw periods are not observed [8]., which These rasidues can be toxic and dangerous to human health. and potentially cause allergic reactions such as rash [9], and long consumptions can lead to . Consumption of animal products containing residual antibiotics for long period can also lead to drug resistant microorganisms [10], tissue damage, toxic effects, gastrointestinal disturbance, carcinogenicity and neurological disorder [5, 11]. In order to protect the health of consumers, maximum residue levels (MRLs) for tetracyclines residues in animal derivatives food has been established by Codex Alimentarius Commission [12]. The levels are 1200ng/g in kidney, 600ng/g in liver and 200ng/g in muscle [10, 12??? 13]. These Codex levels are currently adopted at national level in Tanzania. For effective implementation of these standards, a sensitive and effective method for determining residues levels in poultry meat is needed. There are several methods available for tetracycline residues determination in food of animal origin which has been reported in literature. This method includes screening tests for qualitative determination[4] and those for quantification determination [14, 15]. The available screening test such as agar well diffusion, delvotest SP assay and Four Plate Test (FPT) [4, 11] can...
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...these are just a few of the names given to the plant known as Cannabis Sativa. Lobbyists are currently trying to repeal the federal laws making the growth, production, and possession of medicinal cannabis illegal because of the benefits to people with cancer, glaucoma, and chronic pain. If successful this will also make it legal to grow industrial hemp. Industrial hemp can be used for clothing, nutritional supplements, and paper products; building supplies, automotive construction, and alternative fuel sources. With the legalization of hemp this nation conceivably could negate its dependence on foreign oil and reverse the failing economy. From the birth of this nation up to the 1950s, hemp was grown on large farms and in small family plots. Early settlers understood the necessity of growing hemp for rope and sails used on ships, for cloth to make clothes; even the original flag was made from hemp. In fact there were mandatory grow laws in place for years that made it a crime not to grow hemp. In 1937 the government passed a law (Title 21 U.S.C. Controlled Substance Act) that made it illegal to use marijuana for medicinal purposes. In doing so, they outlawed industrial hemp as well, even though it only contains trace amounts of the substance Tetrahydrocannabinol (THC) that gives Cannabis its effectiveness. Most proponents of legalization are convinced that the government knowingly banned Cannabis because they were in collusion with a number of large industries like DuPont...
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...PARLIAMENT OF ZIMBABWE FIRST SESSION - SIXTH PARLIAMENT FOURTH REPORT OF THE PORTFOLIO COMMITTEE ON LANDS, LAND REFORM, AGRICULTURE, RESETTLEMENT AND WATER DEVELOPMENT ON THE VIABILITY OF THE SUGAR INDUSTRY Presented to Parliament on 6 June 2006 [S.C 15, 2006] ORDERED IN TERMS OF STANDING ORDER No. 151: 1) At the commencement of every session, there shall be as many select committees to be designated according to government portfolios to examine expenditure, administration and policy of government departments and other matters falling under their jurisdictions as the House may by resolution determine and whose members shall be nominated by the Standing Rules and Orders Committee. Such nominations shall take into account the expressed interests, experience or expertise of the members and the political and gender composition of the House. TERMS OF REFERENCE OF PORTFOLIO COMMITTEES S.O 152 Subject to these Standing Orders a Portfolio Committee shall: a) Consider and deal with all Bills and Statutory Instruments which are referred to it by or under resolution of me House or by the Speaker, consider or deal with an appropriation or money bill referred to it by these Standing Orders or by or under resolution of this House; and b) Monitor, investigate, enquire into and make recommendations relating to any aspect of the legislative programme, budget, rationalization, policy formulation or any other matter it...
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...Stats/Modelling Notes Introduction & Summary Computer system users, administrators, and designers usually have a goal of highest performance at lowest cost. Modeling and simulation of system design trade off is good preparation for design and engineering decisions in real world jobs. In this Web site we study computer systems modeling and simulation. We need a proper knowledge of both the techniques of simulation modeling and the simulated systems themselves. The scenario described above is but one situation where computer simulation can be effectively used. In addition to its use as a tool to better understand and optimize performance and/or reliability of systems, simulation is also extensively used to verify the correctness of designs. Most if not all digital integrated circuits manufactured today are first extensively simulated before they are manufactured to identify and correct design errors. Simulation early in the design cycle is important because the cost to repair mistakes increases dramatically the later in the product life cycle that the error is detected. Another important application of simulation is in developing "virtual environments" , e.g., for training. Analogous to the holodeck in the popular science-fiction television program Star Trek, simulations generate dynamic environments with which users can interact "as if they were really there." Such simulations are used extensively today to train military personnel for battlefield situations, at a fraction...
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...ate Aptitude Test in Engineering GATE 2014 Brochure Table of Contents 1. Introduction .............................................................................................................1 2. About GATE 2014 ......................................................................................................1 2.1. Financial Assistance ............................................................................................................................ 1 2.2 Employment ............................................................................................................................................ 2 2.3 Administration ....................................................................................................................................... 2 3.1 Changes Introduced in GATE 2013 that will continue to remain in force for GATE 2014 .......................................................................................................................................................... 3 4.1 Eligibility for GATE 2014 ................................................................................................................... 4 4.2 GATE Papers ............................................................................................................................................ 5 4.3 Zone-Wise List of Cities in which GATE 2014 will be Held ................................................... 6 4.4 Zone-Wise List of Cities for 3rd...
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...Rock Physics Modelling Rock physics is an essential part of any seismic reservoir characterisation project. The rock physics may be as simple as establishing empirical relationships between rock properties or as complex as poroelastic numerical modelling. The sophistication of the modelling will depend on the objectives and the quality and availability of data. Typical objectives of rock physics modelling studies based on well log data are: 1. Quality control of the measured elastic logs: density, p-sonic and s-sonic. Demanding a consistent and meaningful rock physics model can often indicate anomalous and poor quality measurements in the elastic logs that need correction or mitigation. 2. Quality control of petrophysical interpretation. It has been suggested that empirical relationships are more reasonable to use with well log data as it is hard to establish a consistent numerical rock physics model to explain the information from various wells even though they are drilled close by and in the same formations. However, the root of these problems may lie in inconsistencies in the petrophysical interpretations. Insisting on a consistent rock physics model can often highlight inconsistencies within the petrophysical interpretations. 3. Synthesis of elastic logs where missing or the quality is poor. Once a strong relationship has been established between the petrophysical interpretation (or other well log data) and the elastic properties, prediction...
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...efficiency of bacteria has been optimized. Biodegradation of methylene blue and bromophenol blue was demonstrated by monitoring the effects of the different parameters and determining optimal conditions for degradation activity. Introduction Several industrial activities, such as textile dyeing, olive oil extraction and the manufacture of pulp and paper are characterized by intensive water consumption rates. They release huge amounts of more or less coloured effluents into the environment. As far as synthetic dye release is concerned, textile dyeing facilities and the manufacture of dyestuffs are two major polluting sources. In addition, traditional textile dyeing processes generate a large amount of coloured effluents, because about 100 litres of water are required to process 1 kg of dyed fabrics. Moreover, up to 15% of applied dyestuffs are lost to the effluents due to dyeing process inefficiencies. Colour itself could be very pernicious to the receiving water courses not only for aesthetic reasons and toxicity towards many aquatic organisms, but also because coloured compounds reduce water transparency, which, in turn, affects photosynthetic activity, thus causing severe damage to the ecosystems. (Nermeen and...
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