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OCCUPATIONAL HYGIENE ON SODIUM CYANIDE (NaCN) IN A MINING PLANT
MAXWELL P.K.D ANDOH-M00508829.
Rarely a day goes by without a reference in the newspaper, television or on the internet to illnesses or disabilities caused at work. In Some cases, the effects may be reversible but for others are not. In many others, detrimental effects to health cannot be overcome and even shorten life expectancy, thereby increasing the need and values of Occupational hygiene.
Occupational Hygiene may be defined as the use of science and engineering to prevent ill health caused by the environment in which a person works (OH learning). Occupational Hygiene has policies with which it operates in other to understand the risks posed by hazardous agent and thus aid in improving working conditions and work practices. This essay tends to highlight these policies as well as how to go about it in an industrial setting (Mining) where Sodium Cyanide (NaCN) is used. Sodium Cyanide is a hazardous substance in the Mining industry yet it is principal to a successful extraction of mineral of interest, thereby making it less substitutable depending on so many factors considered (such as cost, efficiency, hazards). What is considered above all others is the need to be able to identify and recognize the risk to using cyanide and to minimize it to a reasonably practicable level. Sodium Cyanide is a white powder (like salt). It is used in both solid or in liquid state but sometimes combines with other elements to form a poisonous gas in the extraction process. Some of the potential hazards it poses includes exposure to workers and the release into the environment (Akcil, A. 2006). Workers may be exposed to it in several ways, these ways includes; Ingestion, Inhalation and absorption unto the skin. When this process of exposure takes place, there are so many health effects that occur to the affected person. Many of these health implications include; * When inhaled, it causes harmful corrosive effect to the respiratory tract. It may result in headache, weakness, or laboured breathing nausea and vomiting, which can be followed by weak and irregular heartbeat, unconsciousness, convulsions and death. * When ingested, it is highly poisonous. It is corrosive to the gastro-intestinal tract with burning. Larger doses may produce sudden loss of consciousness and prompt death from respiratory arrest. Smaller but still lethal doses may prolong the illness for one or more hours (Mudder, Botz 2004). * Skin contact with solution may cause severe pain and skin burns and even deep ulcers. Symptoms from the skin exposure are similar to those noted for inhalation (Mudder, Botz 2001).
The above are just a few but major dangers posed by Sodium Cyanide to workers of a mining industry. However, the above being stated, there are several control mechanisms that are employed to safe guard the use of this agent to a reasonably practicable level. Control mechanisms employed includes; Elimination, substitution, isolation, engineering control, administrative control, Personal Protective Equipment. * Elimination- Where possible, eliminating the use of cyanides in the work process. * Substitution- Where practicable, substituting the use of cyanides in a work process with a less hazardous chemical. * Isolation- Isolating cyanides from incompatible substances to avoid dangerous reactions that could generate hydrogen cyanide or other hazardous gases, for example storing cyanides away from acids, oxidising agents and other incompatible substances. Also, Enclosing processes involving cyanides to eliminate the possibility of worker exposure. * Engineering control- Automating handling and processing operations like transferring of cyanides, for example from storage containers to processing vessels, to minimise potential worker contact. * Administrative control- Providing workers with relevant information, training and instructions regarding hazardous substances, the proper use and maintenance of PPE, „ „ awareness of procedures to be followed in case of fire or a spill or leak. Making sure containers are labelled. * Personal Protective Equipment- Wearing impervious gloves when handling cyanides. „ Wearing a protective overalls, wellington boots and face shield or goggles whenever there is the possibility of being splashed with cyanides. Using appropriate respiratory equipment for the concentration of cyanide dust or gas that may be in the air.
These are few but major controlling factors that aim to minimize the effects that may happen as a result of the use of sodium cyanide.

Furthermore, to assess a good Hazard control system, it must be in accordance with Workplace Exposure Limit (WEL).” WEL are occupational exposure limits set in order to help protect the health of workers” (hse.gov). In calculating this, concentrations of hazardous substances in the air are equated over a specified period of time, referred to as a time-weighted average (TWA). Two time periods are used: long-term and short-term. Short-term exposure limits (STELs) are set to help prevent effects such as eye irritation and dermal splash which may occur following exposure for a few minutes (hseni.gov), while long term exposure limit is designed to protect the workforce from concentrations of contaminant, which over a large period of time could cause long term chronic ill health effects (EH40, 2005). In all this what it means is that, the use of this agent must be in the range set out by standardization organisations such as WHO, ISO, OSHA and all the others, in order to help protect workers as well as safe guard the environment.

In conclusion, with all the above been stated there is an important need for periodic arrangements for observing, detecting or recording all principles put in place to help reduce the effects of the hazard at hand. In this case there are several suggestions that can be employed, which are; * Detector Device - This is a Short-term and long term detecting device capable of measuring Hydrogen cyanide gas (HCN) and is available from a number of manufacturers. The short term device provide an inexpensive and simple method for estimating the concentration of HCN in workplace air over a short time period, and can therefore be useful for making screening measurements to identify peak exposures or potential leaks from machines or control equipment. However, it is generally not valid to use short term device detector measurements to calculate time-weighted average exposures for comparison with the WEL. Also, HCN measurements made with detector devices can be imprecise and are affected by positive interference from other oxidising or acidic agents (hse.gov). It is therefore advisable to have both devices available at the work place. * Medical screening- medical surveillance shall be made available to all workers who are occupationally exposed to HCN or cyanide salts. This method may include the following ways; * Annual medical examinations- an initial or mid work and medical history with attention to all symptoms that are carried by patients with exposure to the hazard at hand. * There should be trained physician and treatment kits available on site where there is the potential for the hazard to occur. * If no physician, then there must be an availability of a first aid kit (cdc.gov).
This also are few but major ways by which this hazard may be monitored in order to stay within the reasonably practicable level.

REFERENCE. * Akcil, A. 2006, "Managing cyanide: health, safety and risk management practices at Turkey's Ovacik gold–silver mine", Journal of Cleaner Production, vol. 14, no. 8, pp. 727-735. http://adminopsnet.usc.edu/sites/default/files/all_departments/EHS/SodiumCyanide.pdf; Safety Guideline: Sodium Cyanide,(Accessed 21/10/2015) * http://www.ohlearning.com/about-occupational-hygiene/what-is-oh.aspx;What is occupational hygiene?, (Accessed,22/10/2015) * Western Australia, Department of Minerals and Energy, 1992. Cyanide Management Guideline. Mining Engineering Division, July * http://www.safeworkaustralia.gov.au/sites/SWA/about/Publications/Documents/773/Guide-Cycanide-Poisoning-Workplace.pdf; Gide for preventing and responding to cyanide poisoning in the work place, (Accessed 22/10/2015). * http://www.hse.gov.uk/pubns/priced/eh40.pdf;EH40/2005 Workplace exposure limits containing the list of workplace exposure limits for use with the Control of Substances Hazardous to Health Regulations (as amended), page, 8. (Accessed, 23/10/2015), * http://www.hseni.gov.uk/l5_control_of_substances_hazardous_to_health.pdf; Control of substances hazardous to health, (Accessed,23/10/2015) * http://www.hse.gov.uk/pubns/eh38.pdf;Ozone: Health hazards and control measures Guidance Note EH38, (Accessed 21/10/2015) * http://www.cdc.gov/niosh/pdfs/77-108b.pdf; recommendation for cyanide standards, (Accessed 21/10/2015). * Mudder, T. Botz, M. (2004),”Cyanide and society; a critical review” European Journal of Mineral Processing and Environmental Protection, pp. 62-74. * Mudder T, Botz M. (2001), “A guide to Cyanide”, Mining Environmental Management, pp. 8-12.

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