NUCLEAR POWER: FISSION

The discovery of nuclear fission occurred in 1938 in the buildings of Kaiser Wilhelm Society for Chemistry, today part of the Free University of Berlin, following nearly five decades of work on the science of radioactivity and the elaboration of new nuclear physics that described the components of atoms. In 1911, Ernest Rutherford proposed a model of the atom in which a very small, dense and positively charged nucleus of protons (the neutron had not yet been discovered) was surrounded by orbiting, negatively charged electrons (the Rutherford model). Niels Bohr improved upon this in 1913 by reconciling the quantum behavior of electrons (the Bohr model). Work by Henri Becquerel, Marie Curie, Pierre Curie, and Rutherford further elaborated that the nucleus, though tightly bound, could undergo different forms of radioactive decay, and thereby transmute into other elements. (For example, by alpha decay: the emission of an alpha particle—two protons and two neutrons bound together into a particle identical to a helium nucleus.)
Some work in nuclear transmutation had been done. In 1917, Rutherford was able to accomplish transmutation of nitrogen into oxygen, using alpha particles directed at nitrogen. This was the first observation of a nuclear reaction, that is, a reaction in which particles from one decay are used to transform another atomic nucleus. Eventually, in 1932, a fully artificial nuclear reaction and nuclear transmutation was achieved by Rutherford's colleagues Ernest Walton and John Cockcroft, who used artificially accelerated protons against lithium-7, to split this nucleus into two alpha particles. The feat was popularly known as "splitting the atom", although it was not the modern nuclear fission reaction later discovered in heavy elements, which is discussed below. Meanwhile, the possibility of combining nuclei—nuclear fusion—had been studied in connection with understanding the processes which power stars. The first artificial fusion reaction had been achieved by Mark Oliphant in 1932, using two accelerated deuterium nuclei to create a helium nucleus.
After English physicist James Chadwick discovered the neutron in 1932, Enrico Fermi and his colleagues in Rome studied the results of bombarding uranium with neutrons in 1934. Fermi concluded that his experiments had created new elements with 93 and 94 protons, which the group dubbed ausonium and hesperium. However, not all were convinced by Fermi's analysis of his results. The German chemist Ida Noddack notably suggested in print in 1934 that instead of creating a new, heavier element 93, that "it is conceivable that the nucleus breaks up into several large fragments." However, Noddack's conclusion was not pursued at the time. The experimental apparatus with which Otto Hahn and Fritz Strassmann discovered nuclear fission in 1938. After the Fermi publication, Otto Hahn, Lise Meitner, and Fritz Strassmann began performing similar experiments in Berlin. Meitner, an Austrian Jew, lost her citizenship with the "Anschluss", the occupation and annexation of Austria into Nazi Germany in March 1938, but she fled in July 1938 to Sweden and started a correspondence by mail with Hahn in Berlin. By coincidence, her nephew Otto Robert Frisch, also a refugee, was also in Sweden when Meitner received a letter from Hahn dated 19 December describing his chemical proof that some of the product of the bombardment of uranium with neutrons was barium. Hahn suggested a bursting of the nucleus, but he was unsure of what the physical basis for the results were. Barium had an atomic mass 40% less than uranium, and no previously known methods of radioactive decay could account for such a large difference in the mass of the nucleus. Frisch was skeptical, but Meitner trusted Hahn's ability as a chemist. Marie Curie had been separating barium from radium for many years, and the techniques were well-known.
In nuclear physics and nuclear chemistry, nuclear fission is either a nuclear reaction or a radioactive decay process in which the nucleus of an atom splits into smaller parts. The fission process often produces free neutrons and photons, and releases a very large amount of energy even by the energetic standards of radioactive decay.
Nuclear fission of heavy elements was discovered on December 17, 1938 by German Otto Hahn and his assistant Fritz Strassmann, and explained theoretically in January 1939 by Lise Meitner and her nephew Otto Robert Frisch. Frisch named the process by analogy with biological fission of living cells. It is an exothermic reaction which can release large amounts of energy both as electromagnetic radiation and as kinetic energy of the fragments. In order for fission to produce energy, the total binding energy of the resulting elements must be less negative than that of the starting element.
Fission is a form of nuclear transmutation because the resulting fragments are not the same element as the original atom. The two nuclei produced are most often of comparable but slightly different sizes, typically with a mass ratio of products of about 3 to 2, for common fissile isotopes. Most fissions are binary fissions, but occasionally, three positively charged fragments are produced, in a ternary fission. The smallest of these fragments in ternary processes ranges in size from a proton to an argon nucleus.
Apart from fission induced by a neutron, harnessed and exploited by humans, a natural form of spontaneous radioactive decay is also referred to as fission, and occurs especially in very high-mass-number isotopes. Spontaneous fission was discovered in 1940 by Flyorov, Petrzhak and Kurchatov in Moscow, when they decided to confirm that, without bombardment by neutrons, the fission rate of uranium was indeed negligible, as predicted by Niels Bohr; it wasn't.
The unpredictable composition of the products (which vary in a broad probabilistic and somewhat chaotic manner) distinguishes fission from purely quantum-tunneling processes such as proton emission, alpha decay and cluster decay, which give the same products each time. Nuclear fission produces energy for nuclear power and drives the explosion of nuclear weapons. Both uses are possible because certain substances called nuclear fuels undergo fission when struck by fission neutrons, and in turn emit neutrons when they break apart. This makes possible a self-sustaining nuclear chain reaction that releases energy at a controlled rate in a nuclear reactor or at a very rapid uncontrolled rate in a nuclear weapon.
The amount of free energy contained in nuclear fuel is millions of times the amount of free energy contained in a similar mass of chemical fuel such as gasoline, making nuclear fission a very dense source of energy. The products of nuclear fission, however, are on average far more radioactive than the heavy elements which are normally fissioned as fuel, and remain so for significant amounts of time, giving rise to a nuclear waste problem. Concerns over nuclear waste accumulation and over the destructive potential of nuclear weapons may counterbalance the desirable qualities of fission as an energy source, and give rise to ongoing political debate over nuclear power. Nuclear fission can occur without neutron bombardment as a type of radioactive decay. This type of fission (called spontaneous fission) is rare except in a few heavy isotopes. In engineered nuclear devices, essentially all nuclear fission occurs as a "nuclear reaction" — a bombardment-driven process that results from the collision of two subatomic particles. In nuclear reactions, a subatomic particle collides with an atomic nucleus and causes changes to it. Nuclear reactions are thus driven by the mechanics of bombardment, not by the relatively constant exponential decay and half-life characteristic of spontaneous radioactive processes.
Many types of nuclear reactions are currently known. Nuclear fission differs importantly from other types of nuclear reactions, in that it can be amplified and sometimes controlled via a nuclear chain reaction (one type of general chain reaction). In such a reaction, free neutrons released by each fission event can trigger yet more events, which in turn release more neutrons and cause more fissions.
The chemical element isotopes that can sustain a fission chain reaction are called nuclear fuels, and are said to be fissile. The most common nuclear fuels are 235U (the isotope of uranium with an atomic mass of 235 and of use in nuclear reactors) and 239Pu (the isotope of plutonium with an atomic mass of 239). These fuels break apart into a bimodal range of chemical elements with atomic masses centering near 95 and 135 u (fission products). Most nuclear fuels undergo spontaneous fission only very slowly, decaying instead mainly via an alpha/beta decay chain over periods of millennia to eons. In a nuclear reactor or nuclear weapon, the overwhelming majority of fission events are induced by bombardment with another particle, a neutron, which is itself produced by prior fission events.
Nuclear fissions in fissile fuels are the result of the nuclear excitation energy produced when a fissile nucleus captures a neutron. This energy, resulting from the neutron capture, is a result of the attractive nuclear force acting between the neutron and nucleus. It is enough to deform the nucleus into a double-lobed "drop," to the point that nuclear fragments exceed the distances at which the nuclear force can hold two groups of charged nucleons together, and when this happens, the two fragments complete their separation and then are driven further apart by their mutually repulsive charges, in a process which becomes irreversible with greater and greater distance. A similar process occurs in fissionable isotopes (such as uranium-238), but in order to fission, these isotopes require additional energy provided by fast neutrons (such as those produced by nuclear fusion in thermonuclear weapons).
The liquid drop model of the atomic nucleus predicts equal-sized fission products as an outcome of nuclear deformation. The more sophisticated nuclear shell model is needed to mechanistically explain the route to the more energetically favorable outcome, in which one fission product is slightly smaller than the other. A theory of the fission based on shell model has been formulated by Maria Goeppert Mayer. The most common fission process is binary fission, and it produces the fission products noted above, at 95±15 and 135±15 u. However, the binary process happens merely because it is the most probable. In anywhere from 2 to 4 fissions per 1000 in a nuclear reactor, a process called ternary fission produces three positively charged fragments (plus neutrons) and the smallest of these may range from so small a charge and mass as a proton (Z=1), to as large a fragment as argon (Z=18). The most common small fragments, however, are composed of 90% helium-4 nuclei with more energy than alpha particles from alpha decay (so-called "long range alphas" at ~ 16 MeV), plus helium-6 nuclei, and tritons (the nuclei of tritium). The ternary process is less common, but still ends up producing significant helium-4 and tritium gas buildup in the fuel rods of modern nuclear reactors.
The fission of a heavy nucleus requires a total input energy of about 7 to 8 million electron volts (MeV) to initially overcome the nuclear force which holds the nucleus into a spherical or nearly spherical shape, and from there, deform it into a two-lobed ("peanut") shape in which the lobes are able to continue to separate from each other, pushed by their mutual positive charge, in the most common process of binary fission (two positively charged fission products + neutrons). Once the nuclear lobes have been pushed to a critical distance, beyond which the short range strong force can no longer hold them together, the process of their separation proceeds from the energy of the (longer range) electromagnetic repulsion between the fragments. The result is two fission fragments moving away from each other, at high energy.
About 6 MeV of the fission-input energy is supplied by the simple binding of an extra neutron to the heavy nucleus via the strong force; however, in many fissionable isotopes, this amount of energy is not enough for fission. Uranium-238, for example, has a near-zero fission cross section for neutrons of less than one MeV energy. If no additional energy is supplied by any other mechanism, the nucleus will not fission, but will merely absorb the neutron, as happens when U-238 absorbs slow and even some fraction of fast neutrons, to become U-239. The remaining energy to initiate fission can be supplied by two other mechanisms: one of these is more kinetic energy of the incoming neutron, which is increasingly able to fission a fissionable heavy nucleus as it exceeds a kinetic energy of one MeV or more (so-called fast neutrons). Such high energy neutrons are able to fission U-238 directly (see thermonuclear weapon for application, where the fast neutrons are supplied by nuclear fusion). However, this process cannot happen to a great extent in a nuclear reactor, as too small a fraction of the fission neutrons produced by any type of fission have enough energy to efficiently fission U-238 (fission neutrons have a mode energy of 2 MeV, but a median of only 0.75 MeV, meaning half of them have less than this insufficient energy).
Among the heavy actinide elements, however, those isotopes that have an odd number of neutrons (such as U-235 with 143 neutrons) bind an extra neutron with an additional 1 to 2 MeV of energy over an isotope of the same element with an even number of neutrons (such as U-238 with 146 neutrons). This extra binding energy is made available as a result of the mechanism of neutron pairing effects. This extra energy results from the Pauli Exclusion Principle allowing an extra neutron to occupy the same nuclear orbital as the last neutron in the nucleus, so that the two form a pair. In such isotopes, therefore, no neutron kinetic energy is needed, for all the necessary energy is supplied by absorption of any neutron, either of the slow or fast variety (the former are used in moderated nuclear reactors, and the latter are used in fast neutron reactors, and in weapons). As noted above, the subgroup of fissionable elements that may be fissioned efficiently with their own fission neutrons (thus potentially causing a nuclear chain reaction in relatively small amounts of the pure material) are termed "fissile." Examples of fissile isotopes are U-235 and plutonium-239.
Typical fission events release about two hundred million eV (200 MeV) of energy for each fission event. The exact isotope which is fissioned, and whether or not it is fissionable or fissile, has only a small impact on the amount of energy released. This can be easily seen by examining the curve of binding energy (image below), and noting that the average binding energy of the actinide nuclides beginning with uranium is around 7.6 MeV per nucleon. Looking further left on the curve of binding energy, where the fission products cluster, it is easily observed that the binding energy of the fission products tends to center around 8.5 MeV per nucleon. Thus, in any fission event of an isotope in the actinide's range of mass, roughly 0.9 MeV is released per nucleon of the starting element. The fission of U235 by a slow neutron yields nearly identical energy to the fission of U238 by a fast neutron. This energy release profile holds true for thorium and the various minor actinides as well.
By contrast, most chemical oxidation reactions (such as burning coal or TNT) release at most a few eV per event. So, nuclear fuel contains at least ten million times more usable energy per unit mass than do chemical fuel. The energy of nuclear fission is released as kinetic energy of the fission products and fragments, and as electromagnetic radiation in the form of gamma rays; in a nuclear reactor, the energy is converted to heat as the particles and gamma rays collide with the atoms that make up the reactor and its working fluid, usually water or occasionally heavy water or molten salts.
When a uranium nucleus fissions into two daughter nuclei fragments, about 0.1 percent of the mass of the uranium nucleus appears as the fission energy of ~200 MeV. For uranium-235 (total mean fission energy 202.5 MeV), typically ~169 MeV appears as the kinetic energy of the daughter nuclei, which fly apart at about 3% of the speed of light, due to Coulomb repulsion. Also, an average of 2.5 neutrons are emitted, with a mean kinetic energy per neutron of ~2 MeV (total of 4.8 MeV). The fission reaction also releases ~7 MeV in prompt gamma ray photons. The latter figure means that a nuclear fission explosion or criticality accident emits about 3.5% of its energy as gamma rays, less than 2.5% of its energy as fast neutrons (total of both types of radiation ~ 6%), and the rest as kinetic energy of fission fragments (this appears almost immediately when the fragments impact surrounding matter, as simple heat). In an atomic bomb, this heat may serve to raise the temperature of the bomb core to 100 million kelvin and cause secondary emission of soft X-rays, which convert some of this energy to ionizing radiation. However, in nuclear reactors, the fission fragment kinetic energy remains as low-temperature heat, which itself causes little or no ionization.
So-called neutron bombs (enhanced radiation weapons) have been constructed which release a larger fraction of their energy as ionizing radiation (specifically, neutrons), but these are all thermonuclear devices which rely on the nuclear fusion stage to produce the extra radiation. The energy dynamics of pure fission bombs always remain at about 6% yield of the total in radiation, as a prompt result of fission.
The total prompt fission energy amounts to about 181 MeV, or ~ 89% of the total energy which is eventually released by fission over time. The remaining ~ 11% is released in beta decays which have various half-lives, but begin as a process in the fission products immediately; and in delayed gamma emissions associated with these beta decays. For example, in uranium-235 this delayed energy is divided into about 6.5 MeV in betas, 8.8 MeV in antineutrinos (released at the same time as the betas), and finally, an additional 6.3 MeV in delayed gamma emission from the excited beta-decay products (for a mean total of ~10 gamma ray emissions per fission, in all). Thus, about 6.5% of the total energy of fission is released sometime after the event, as non-prompt or delayed ionizing radiation, and the delayed ionizing energy is about evenly divided between gamma and beta ray energy.
In a reactor that has been operating for some time, the radioactive fission products will have built up to steady state concentrations such that their rate of decay is equal to their rate of formation, so that their fractional total contribution to reactor heat (via beta decay) is the same as these radio isotopic fractional contributions to the energy of fission. Under these conditions, the 6.5% of fission which appears as delayed ionizing radiation (delayed gammas and betas from radioactive fission products) contributes to the steady-state reactor heat production under power. It is this output fraction which remains when the reactor is suddenly shut down (undergoes scram). For this reason, the reactor decay heat output begins at 6.5% of the full reactor steady state fission power, once the reactor is shut down. However, within hours, due to decay of these isotopes, the decay power output is far less. See decay heat for detail.
The remainder of the delayed energy (8.8 MeV/202.5 MeV = 4.3% of total fission energy) is emitted as antineutrinos, which as a practical matter, are not considered "ionizing radiation." The reason is that energy released as antineutrinos is not captured by the reactor material as heat, and escapes directly through all materials (including the Earth) at nearly the speed of light, and into interplanetary space (the amount absorbed is minuscule). Neutrino radiation is ordinarily not classed as ionizing radiation, because it is almost entirely not absorbed and therefore does not produce effects (although the very rare neutrino event is ionizing). Almost all of the rest of the radiation (6.5% delayed beta and gamma radiation) is eventually converted to heat in a reactor core or its shielding.
Some processes involving neutrons are notable for absorbing or finally yielding energy — for example neutron kinetic energy does not yield heat immediately if the neutron is captured by a uranium-238 atom to breed plutonium-239, but this energy is emitted if the plutonium-239 is later fissioned. On the other hand, so-called delayed neutrons emitted as radioactive decay products with half-lives up to several minutes, from fission-daughters, are very important to reactor control, because they give a characteristic "reaction" time for the total nuclear reaction to double in size, if the reaction is run in a "delayed-critical" zone which deliberately relies on these neutrons for a supercritical chain-reaction (one in which each fission cycle yields more neutrons than it absorbs). Without their existence, the nuclear chain-reaction would be prompt critical and increase in size faster than it could be controlled by human intervention. In this case, the first experimental atomic reactors would have run away to a dangerous and messy "prompt critical reaction" before their operators could have manually shut them down (for this reason, designer Enrico Fermi included radiation-counter-triggered control rods, suspended by electromagnets, which could automatically drop into the center of Chicago Pile-1). If these delayed neutrons are captured without producing fissions, they produce heat as well.
Critical fission reactors are the most common type of nuclear reactor. In a critical fission reactor, neutrons produced by fission of fuel atoms are used to induce yet more fissions, to sustain a controllable amount of energy release. Devices that produce engineered but non-self-sustaining fission reactions are subcritical fission reactors. Such devices use radioactive decay or particle accelerators to trigger fissions.
Critical fission reactors are built for three primary purposes, which typically involve different engineering trade-offs to take advantage of either the heat or the neutrons produced by the fission chain reaction: power reactors are intended to produce heat for nuclear power, either as part of a generating station or a local power system such as a nuclear submarine. Research reactors are intended to produce neutrons and/or activate radioactive sources for scientific, medical, engineering, or other research purposes. Breeder reactors are intended to produce nuclear fuels in bulk from more abundant isotopes. The better known fast breeder reactor makes 239Pu (a nuclear fuel) from the naturally very abundant 238U (not a nuclear fuel). Thermal breeder reactors previously tested using 232Th to breed the fissile isotope 233U (thorium fuel cycle) continue to be studied and developed.
While, in principle, all fission reactors can act in all three capacities, in practice the tasks lead to conflicting engineering goals and most reactors have been built with only one of the above tasks in mind. (There are several early counter-examples, such as the Hanford N reactor, now decommissioned). Power reactors generally convert the kinetic energy of fission products into heat, which is used to heat a working fluid and drive a heat engine that generates mechanical or electrical power. The working fluid is usually water with a steam turbine, but some designs use other materials such as gaseous helium. Research reactors produce neutrons that are used in various ways, with the heat of fission being treated as an unavoidable waste product. Breeder reactors are a specialized form of research reactor, with the caveat that the sample being irradiated is usually the fuel itself, a mixture of 238U and 235U. For a more detailed description of the physics and operating principles of critical fission reactors, see nuclear reactor physics. For a description of their social, political, and environmental aspects, see nuclear power.
Nuclear energy is the only proven technology that can deliver base load electricity on a large scale, 24 hours a day, 7 days a week, regardless-of-the-weather, without producing carbon dioxide emissions. Nuclear power plants emit no carbon pollution—no carbon monoxide, no sulfur oxides and no nitrogen oxides to the atmosphere. And, nuclear power plants will not contaminate streams and rivers with mercury. Nuclear Fission creates no air pollution, but it does create a small amount of radioactive by-products. Opponents of nuclear energy believe a nuclear power plant accident would cause toxic radioactive nuclear material to be released into the environment. Fear of exposure to Nuclear Radiation has created public opposition to nuclear energy. However, even with the potential danger of nuclear radiation, nuclear energy technology has a long history of safe operation. Worldwide nuclear electricity has accumulated over 10,000 reactor-years of operating experience. Today, the issue of nuclear energy safety and nuclear waste disposal is not a technical problem but one of public and political acceptance.