...Microbial Degradation of Hydrocarbons Vijay Kothari*, Meera Panchal, Namrata Srivastava Institute of Science, Nirma University *Corresponding author: vijay.kothari@nirmauni.ac.in; vijay23112004@yahoo.co.in Abstract Hydrocarbon contamination in the environment has been a notable problem since years. Particularly the major oil spills in last few decades, and resulting loss to biodiversity has brought public attention to this problem. Bioremediation is a promising approach for recovery of environmental sites contaminated with crude oil and other hydrocarbons. Many microorganisms have been identified to possess hydrocarbon degradation potential. This review covers an overview of common hydrocarbon pollutants, microbes known as hydrocarbon degraders, major pathways and enzymes involved therein, factors affecting hydrocarbon degradation, and various approaches employed to exploit degrading capacity of microbes for remedial purpose. In addition to making use of inherent catabolic ability of degrader populations, metabolic engineering can be of considerable value in dealing with the problem of hydrocarbon contamination. Keywords: Bioremediation, Oxygenase, Biomagnification, Cometabolism, Consortium, Biosurfactant. Introduction Hydrocarbon (HC) group of compounds consist of hydrogen and carbon in their structure. As petrochemical industries are flourishing worldwide, HC contamination has become one of the major environmental problems faced globally. Environment is particularly being...
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...What are Polynuclear Aromatic Hydrocarbons? Polynuclear aromatic hydrocarbon or polycyclic aromatic hydrocarbons (PAHs) are a group of toxic organic compounds. These organic contaminants are often byproducts of the processing of crude oil or incomplete combustion consisting of many aromatic rings joined together. (1) Occurrence of Polynuclear Aromatic Hydrocarbons in Foods PAHs tend to be Lipophilic in nature and there occurrence in foods can be linked to contamination by soil, water and/or air or from cooking practices at home such as roasting, grilling smoking etc.(2) High temperatures and exposure to sunlight decreases the concentration in food substances. There are over 500 PAHs but only 15 have been identified that affect foods. Figure 1 shows a list of the fifteen PAHs along with their structures. (see appendix) Sources of airborne PAHs are forest fires and volcanoes. The most important stationary anthropogenic sources include residential burning of wood, oil, gas and charcoal as well as industrial power generation, incineration, production of aluminium, iron and steel, petroleum catalytic cracking and production of asphalt, coal tar and coke. The most important mobile sources are vehicular exhausts from gasoline and diesel-powered engines. In combustion processes the formation of PAHs is reduced when combustion is more thoroughly performed but this will increase the formation of nitrogen oxides. . Formation of PAHs The formation of PAHs in foods is varied based...
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...The case of Bates v. Alumina, Inc. summarized The case is divided into three parts, to which the paper will later refer when discussing the Team Buddy recommendations to the CEO of Alumina, Inc. 1. In May, 2004, the Erehwon Reporter published a scathing article against Alumina, Inc., in which Kelly Bates charged that Alumina, Inc. had discharged polycyclic aromatic hydrocarbons (PAHs) into the waters of Lake Dira in violation of EPA standards, and therefore was responsible for her child contracting leukemia. Alumina, Inc. responded by ordering an internal audit, which concluded that it was not producing PAHs above the EPA standard levels. 2. Bates and the Erehwon Reporter then approached the EPA to obtain the environmental audit report that documented the Alumina, Inc. violation of the Clean Water Act five years ago. The EPA notified Alumina Inc. that disclosure of information under the Freedom of Information Act (FOIA) was being considered. Alumina, Inc. disclosed the environmental audit information to The Erehwon Reporter without releasing any confidential information. 3. Bates then threatened to file a million-dollar personal injury lawsuit against Alumina, Inc. to recover compensatory and punitive damages. Bates alleged that Alumina’s negligent conduct, evident in the “serious violation” of environmental laws five years ago, was the proximate cause of her daughter’s leukemia. Through the mediation of a neutral third party, AAA, a confidential settlement provided...
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...Topic Name Institution Outline Introduction 3 Sampling Methods 3 Active Sampling 4 Passive Sampling 4 Passive Samplers Applied 4 Purpose of the Study 5 Materials and Methods 5 Sampling site 5 Figure 1 6 Materials 6 Standards Applied 6 Methods and Procedures 8 Preparation of the samples and sampling 8 Analysis 8 Results and Discussion 9 Conclusion 13 References 14 Altitude and Seasonally Profiled Air Concentrations of Polycyclic Aromatic Hydrocarbons (PAH) Determined with PDMS (TWISTER®) in Taurus Mountains, Turkey Introduction To monitor environmental pollution and its health effects, atmospheric data of persistent organic pollutants (POP) has been collected for some time to help in evaluating the cause. Polycyclic aromatic hydrocarbons (PAH) have been in focus of attention for years. In 1982, the US Environmental Protection Agency (EPA) come forth with a thorough study on the emissions and health effects of benzo (a) pyrene and other PAHs (United States Environmental Protection Agency, 1982). According to the report, the carcinogenetic effect of benzo (a) pyrene was already proven and other PAHs were suspected to have similar effects. The US EPA categorized these PAHs and selected 16 compounds that were found and monitored to prove the claims. They are were named as the sixteen EPA-PAHs. The emission sources for these compounds that were presented in the study as having...
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...Business Regulation Simulation Alumnia Inc. is a $4 billion dollar company that operates in eight countries around the world with 70% of its sales in the United States. They are located by Lake Dira in the state of Erehwon. Alumnia Inc. business interests are in automotive components and manufacture “packaging materials, bauxite mining, alumina refining and aluminum smelting. Alumuna falls under jurisdiction of region 6” of the Environmental Protection Agency (EPA) (University of Phoenix, 2002). The company was cited by the EPA 5 years ago for a Polycyclic Aromatic Hydrocarbon (PAH) discharge in nearby Lake Dira. Five years later, Kelly Bates accused Alumina Inc. of contaminating the waters of Lake Dira with PAHs thus causing her 10 year old daughter’s leukemia. “Bates also alleges that her daughter’s disease may be as old as Alumina’s first instance of environmental law violation” (University of Phoenix, 2002). These allegations were reviewed by Alumina’s legal counsel and handled to keep the company from further litigation that would only serve to tarnish the company’s reputation. This paper will illustrate key facts, regulations and legal issues in the Business Regulation Simulation. It will address the values, conflicts among the stakeholders and ethical dilemmas with the multibillion dollar company. A legal counsel’s summary of basic issues and the action handling the environmental regulatory topic will be explored. Based on table 1, a risk analysis and alternative...
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...Synopsis In the interactive simulation in negligence regulatory compliance, Alumina Inc. is an aluminum producing company that operates in eight countries around the world. The company has business interests in automotive components, the manufacturing of packaging materials, bauxite mining, alumina refining, and aluminum smelting. Although Alumina operates in many countries, the United States accounts for nearly 70% of Alumina’s sales figures. (UoP, 2002 ) Five years ago, in a routine Environmental Protection Agency (EPA) compliance evaluation, Alumina was reported to be in violation of environmental discharge norms. According to the evaluation results, the Polycyclic Aromatic Hydrocarbons (PAH) concentration in water test samples were above the prescribed limit. (UoP, 2002) As a result, the EPA ordered a mandatory clean up; to which Alumina immediately complied and upon an EPA audit, received a report as the issue being “corrected.” Furthermore, up to the date of the EPA’s findings and the five years following, Alumina has had no other blemishes on its environmental regulation compliance record. Now, five years later, a story in the local newspaper, The Erehwon Reporter, reports that Kelly Bates, a 38-year-old single mother, is making accusations that Alumina has repeatedly contaminated the water of Lake Dira with carcinogenic effluents; which is being blamed for the proximate cause of her 10 year daughter’s diagnosis of leukemia. Risks The threat of a lawsuit presents...
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...ODO, EMMANUEL OGECHUKWU No. 6, Rasaq Onimole Street, By Hostel Bus-Stop, Ikotun Egbe, Lagos. Tel No: 08030924110, 08033651771 E-mail: odoh42007@gmail.com CAREER OBJECTIVE: To work with dedicated professionals in any organization, where I can utilize my skills and initiative in realizing corporate goals as well as acquiring relevant skills for more proficiency. I am self motivated, articulate, able to work under pressure, having the ability to reach targeted goals, ability to learn fast and adapt to changes and able to work with little or no supervision. SKILLS AND COMPETENCES: * Interpersonal Skill * Presentational Skill * Computer Skill * Ability to propose innovative and workable alternatives or solutions. * Global participation and personal development (Research) GENERAL INFORMATION: Date of Birth : 23rd April, 1980 Sex : Male State of Origin : Enugu State Nationality : Nigerian EDUCATIONAL QUALIFICATIONS WITH DATES: * Certificates in Seamanship, Regional Maritime University Accra Ghana 2008 * Certificate in Health Safety and Environmental Management in Oil & Gas. 2008 * Proficiency Certificate in Nigeria Institute of Management (NIM) 2007 * Diploma Certificate in Computer Appreciation. 2007 * Bachelor’s Degree; B.Sc Industrial Chemistry – Abia State University, Uturu. 2005 * Senior Secondary School Certificate – Community Secondary School Ogbodu – Aba, Enugu State. 1997 * General Certificate...
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...government where it operates; the company must follow legal, social and environmental regulations in order to be a successful company. Alumina Inc.'s legal issues can be a potential damaging lawsuit brought up by a local resident a mother who filed a five-million dollar personal injury lawsuit against Alumina, Inc. to recover compensatory and punitive damages” (Simulation, 2008). “Most of the environmental laws, such as the Clean Air and Water Acts, contain citizen enforcement provisions, which grant private citizens and groups the standing to sue to challenge failures to comply with the environmental laws.” (Reed, Morehead, Shedd, & Corley, 2005). She accused Alumina of repeatedly contaminating the waters with carcinogenic effluents from its industrial processes. Most detrimental allegation is her claim that her ten-year-old daughter sickness is the result of consuming the polynuclear Aromatic Hydrocarbons (PAH) contaminated water that Alumina had discharged five years earlier (Simulation, 2008). Alumina was found to have high concentration levels of Polynuclear Aromatic Hydrocarbons (PAH) in its environmental expulsion standards by the EPA. The damaging accusations from Ms. Bates were reported on Erehwon newspaper, which caused grave concern to the company management team; because of the possibility of the company image being tainted and its responsibility in complying with environmental regulations and issues, Alumina inc had to react and fast, the challenge was to find a costless...
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...Extension and Revision of the von Baeyer System for Naming Polycyclic Compounds (Including Bicyclic Compounds) (IUPAC Recommendations 1999) Synopsis, Preamble, VB-1 to VB-5 Contents of Section Synopsis Preamble VB-1 Definitions and Terminology VB-2 Main Ring VB-3 Naming Hydrocarbon Bicylic Systems VB-4 Numbering of Bicyclic Systems VB-5 Main Bridge References for this Section [pic] Synopsis These recommendations document the von Baeyer system for naming polycyclic ring systems described in Rules A-31, A-32 and B-14 of the Nomenclature of Organic Chemistry, Sections A, B, C, D, E, F and H, 1979 and R-2.4.2 of A Guide to IUPAC Nomenclature of Organic Compounds, 1993 and extend the system to cover more complex cases. It provides guidance on the naming of ring systems which previously the rules did not cover. The method is to identify the main ring and main bridge which provide the basic bicyclic system and to number these atoms. Then all further bridges, whether or not they include additional atoms, are identified by indicating not only the number of atoms but also the two atoms to which the bridge is attached. The final name also indicates the number of rings and the total number of skeletal atoms in the ring system. Heteroatoms, unsaturation and substituents are indicated in the usual way. Preamble This system of naming polycyclic compounds was first developed for bicyclic compounds by von Baeyer (ref 1) and was extended to tricyclic systems by Buchner and Weigand...
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...violation or perceived violation can open the business to questions of negligence and both legal and financial responsibility. To minimize these instances and create a business that has limited liability concerns it is important that management creates and maintains an effective risk management model for the business. Using the simulation provided, our team has identified legal issues and tort violations presented in this scenario, defined a process for managing risk factors, and identified relevant factors in determining what steps to take after a violation occurred. Legal Issues and Principles In the scenario presented Alumina had one Environmental Protection Agency (EPA) violation five years earlier for unacceptable levels of polycyclic aromatic hydrocarbons (PAHs) found in nearby Lake Dira. This contamination was found to have occurred as a direct effect of Alumina’s refining operations. PAHs are carcinogenic chemicals released during refining activities as “suspended particulate matter in the air” (Breast Cancer Fund, n.d.). The company complied fully with the EPA’s order to clean up the contamination as evidenced by a subsequent agency audit. As stated in the scenario; aside from “this one incident, Alumina Inc. has enjoyed a good overall environmental regulation compliance record” (University of Phoenix, 2002). The company is currently facing allegations from a local resident who believes Alumina continues to contaminate the river water with PAHs and has caused...
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...Occupational lung cancer and smoking: a review in the light of current theories of carcinogenesis ALAN C. CHOVIL, MA, MB, B CHIR MPH, DAB PREy MED This paper considers modern theories of carcinogenesis as they apply to the induction of lung cancer by tobacco smoking and occupational exposure to carcinogens. Some of the known and postulated factors affecting carcinogenesis are discussed, with particular reference to syncarcinogenesis and thresholds. Factors affecting the intensity of smoking exposure are reviewed, and the generally accepted occupational lung carcinogens are listed. Relative risks for the various carcinogens according to smoking status (where known) are presented. The carcinogens are considered individually, and known or postulated interactions with smoking are discussed. It is concluded that the effects of lung carcinogens can be explained on the basis of current theories that support a rational definition of priorities for the prevention of occupational lung cancer. Cette etude s'interesse aux th6ories modernes de Ia carcinogenese telles qu'elles s'appliquent a l'induction du cancer du poumon par le tabac et par les risques du metier relie aux carcinogenes. Ouelques facteurs connus ou postules relatifs a Ia carcinogenese sont discutes, avec un interAt particulier pour Ia syncarcinogenese et les seuils de tol6rance. Les facteurs qui influencent l'intensite de l'exposition au tabac sont revus et on fait l'inventaire des carcinogenes pulmonaires relies au metier...
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...well as being published by the Waterbird society. Summary 6 FDA risk assessment of seafood contamination after BP oil spill The FDA did a risk assessment of to protect people from polycyclic aromatic hydrocarbons(PAH) adsorbed in seafood from the oil spill. After the spill there was a multiagency assessment done by all states bordering the gulf, and it was determined that the cancer risk of regular consumption would be 1x10^-5. The FDA then concluded that there is not a large risk of cancer over a lifetime of exposure. The acceptable risk range is between of PAH in seafood causing cancer is 1x10^-4 to 1x10^-6. The actual cancer risk from seafood contaminated with PAH is believed to be below 1x10^-4 and could very well be as low as zero. The FDA does oppose the risk assessment of Rotkin Ellman when it comes to the likelihood of seafood contaminated with PAH causing cancer in humans. Most of the data used however is based on average lifetime body weights as well as average lifespan of a human population. The author then goes into depth about the many variables and methods used to collect the information to calculate the risk assessment. This article is relevant because it gives insight on two different studies done on the cancer risk of consuming seafood contaminated with polycyclic aromatic hydrocarbons. The article is credible because it is published by The NAtional Institute of Environmental Health Sciences, also this article was found on jstor. ...
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...Maybe you’re going to a party or maybe you have a date. Whatever the reason, women tend to pile tons of make up on their without knowing the chemistry behind it all. What exactly is chemistry? Chemistry is the science that systematically studies the composition, properties, and activities of organ and inorganic substances and various elementary forms of matter. So what chemistry is used in the process of developing the products that enhance our beauty? Mascara, it’s the most basic, yet need-to-have by every women. This beauty product however is not easy to make. Most ingredients required in this product undergo the process of chemistry. One of these examples is the ingredient chromium oxide (which is used as a pigment). In order to create chromium,...
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...1981 - Bob Rau leads Polycyclic Architecture project at TRW/ESL 1983 - Josh Fisher describes ELI-512 VLIW design and trace scheduling 1983-1988 - Rau at Cydrome works on VLIW design called the Cydra-5, but the company folds in 1988 1984-1990 - Fisher at Multiflow works on VLIW design called the Trace, but the company folds in 1990 1988 - Dick Lampman at HP hires Bob Rau and Mike Schlansker from Cydrome and also gets IP rights from Cydrome 1989 - Rau and Schlansker begin the FAST (Fine-grained Architecture and Software Technologies) research project at HP; they later develop the HP PlayDoh architecture 1990-1993 - Bill Worley leads PA-WW (Precision Architecture Wide-Word) effort at HP Labs to be the successor to the PA-RISC architecture; it was also called SP-PA (Super-Parallel Processor Architecture) and SWS (Super WorkStation) HP hires Josh Fisher, input to PA-WW input to PA-WW from Hitachi team, led by Yasuyuki Okada November 1991 - Hans Mulder joins Intel to start work on a 64-bit architecture July 1992 - Worley recommends HP seek a semiconductor manufacturing partner 1993 - HP starts effort to develop PA-WW as a product December 1993 - HP investigates partnership with Intel June 1994 - announcement of cooperation between HP and Intel; PA-WW used as starting point for joint design; John Crawford of Intel leads the joint team 1997 - the term EPIC is coined October 1997 - Microprocessor Forum presentations by Intel and HP July 1998 - Carole Dulong of Intel publishes...
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...Take one of the health risk assessments located on the LRC website. After completing the assessment, write a 500- to 750-word summary that includes the following: • Description of the disease • Risk factors for the disease • Lifestyle choices you can make in your life to decrease your modifiable risk factors for this disease Breast cancer is a type of cancer originating from breast tissue, most commonly from the inner lining of milk ducts or the lobules that supply the ducts with milk. Cancers originating from ducts are known as ductal carcinomas, while those originating from lobules are known as lobular carcinomas. Breast cancer occurs in humans and other mammals. The primary risk factors for breast cancer are female sex and older age.[19] Other potential risk factors include: genetics,[20] lack of childbearing or lack of breastfeeding,[21] higher levels of certain hormones,[22][23] certain dietary patterns, and obesity. Recent studies have indicated that exposure to light pollution is a risk factor for the development of breast cancer.[24] Smoking tobacco appears to increase the risk of breast cancer, with the greater the amount smoked and the earlier in life that smoking began, the higher the risk.[25] In those who are long-term smokers, the risk is increased 35% to 50%.[25] A lack of physical activity has been linked to ~10% of cases.[26] The association between breast feeding and breast cancer has not been clearly determined; some studies...
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