...Chemistry note on thermodynamics A born haber cycle= a thermochemical cycle that includes all the enthalpy changes involved in the formation of an ionic compound. e.g the born haber cycle for sodium chloride if we know any five we can calculate the other: starting from the elements in their standard states. Na s -> Na g +108kjmol-1 ½ CL2-> Cl g +122kjmol-1 Na g -> Na+ + e- +496kjmol-1 Cl g + e+ -> Cl- g -349kjmol-1 Na s + ½ Cl2 -> NaCl s -411kjmol-1 When drawing the born haber cycles: * Make up a rough scale 1 line of paper to 100kjmol-1 * Plan out roughly first to avoid going off the top or bottom of the paper. The zero line representing elements in their standard state will need to be in the middle of the paper. * Remember to put in the sign of each enthalpy change and an arrow to show its direction. Possitive enthalpy changes go up, negative enthalpy changes go down. Using born haber cycle we are able to see the formation of an ionic compound from its elements is an exothermic process. This is mainly due to the large amount of energy given out when the lattice forms. 1. Elements in their standard states. This is the energy zero of the diagram 2. Add in the atomisation of sodium. This is positive, drawn uphill. 3. Add in the atomisation of chlorine. This is positive, drawn uphill. 4. Add in the ionisation of sodium, also posstive, drawn uphill. 5. Add in the electron affinity of chlorine. This is negative...
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...closed system (a fixed mass) in two distinct forms: heat and work. For control volumes, energy can also be transferred by mass flow. An energy transfer to or from a closed system is heat if it is caused by a temperature difference. Otherwise it is work, and it is caused by a force acting through a distance. We start this chapter with a discussion of various forms of energy and energy transfer by heat. We then introduce various forms of work and discuss energy transfer by work. We continue with developing a general intuitive expression for the first law of thermodynamics, also known as the conservation of energy principle, which is one of the most fundamental principles in nature, and we then demonstrate its use. Finally, we discuss the efficiencies of some familiar energy conversion processes, and examine the impact on energy conversion on the environment. Detailed treatments of the first law of thermodynamics for closed systems and control volumes are given in Chaps. 4 and 5, respectively. Objectives The objectives of Chapter 2 are to: • Introduce the concept of energy and define its various forms. • Define the nature of internal energy. • Define the concept of heat and the terminology associated with energy transfer by heat. • Discuss the three...
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...[pic] Activity 1.3.3 Thermodynamics Introduction Think back to the last time someone complained about a door being left open. What did you notice about the temperature within the room as a result of the open door? In Activity 1.3.3 you will investigate the effects of work, thermo energy, and energy on a system, as in the case of the room with the door left open. Procedure Answer the following questions as your teacher discusses the Introduction to Thermodynamics presentation. 1. Define thermodynamics. 2. List three examples of a thermodynamic system. a. b. c. 3. Define thermal energy. 4. Define temperature. |Scale |Freezing point of water |Boiling point of water | |Celsius | | | |Fahrenheit | | | |Kelvin | | | 5. Fill in the table below with the correct scale and unit. 6. Define absolute zero. 7. Define thermal equilibrium. 8. Define the Zeroth...
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...HW4 Thermodynamics Answer Key | Procedure Answer the following questions as your teacher discusses the Introduction to Thermodynamics presentation. List three examples of a thermodynamic system. a. Nuclear power b. Electronic heat sink c. Rocket launch Define thermal energy. * Kinetic energy in transit from one object to another due to temperature difference Define temperature. * The average kinetic energy of particles in an object * Define absolute zero. All kinetic energy is removed - 0K Define thermal equilibrium. Touching objects within a system reach the same temperature Define the 1st Law of Thermodynamics. Thermal energy can change form and location, but it cannot be created or destroyed. List two ways thermal energy can be increased in a system. d. Adding thermal energy e. Performing work on the system Define the 2nd Law of Thermodynamics. Thermal energy flows from hot to cold. Define entropy. The measure of how evenly distributed heat is within a system Define convection. The transfer of thermal energy by movement of fluid (liquid or gas) List two examples of convection. f. Weather g. Boiler systems Define conduction. The transfer of thermal energy within an object or between objects from molecule to molecule List two examples of conduction. h. Metal spoon i. Heat through a wall * Conduction Equations: Define...
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...Those notes can only be sequenced so many times before they are repeated by a new musician and called “original”. Intellectual property has been protected in the courts systems, but has favored personal interest over creativity and borrowing. In the case of Weber vs. Repp for example, Repp was claiming to be the owner of the copied Catholic folk music stolen to create music by Weber. With help from a lawyer, it is proven that Weber wrote a song previous to the music and songs by Repp. It was demonstrated that Weber wrote a song, Repp wrote another song sounding similar, and then Weber wrote the song in question. This showing that Weber borrowed from himself and Repp borrowed from him. The musical notes played in the same sequence were copied by both composers and therefore the courts dismissed the case, musical notes are not owned by any one composer. It does not matter what you copy but how much you choose to take. The idea behind Gladwell’s argument is that borrowing some to be creative is and needs to be acceptable in the eyes of “plagiarism...
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...Thermodynamics is a branch of physics that applies to heat and temperature’s relation to work and energy. There are four well-known laws of thermodynamics. The zeroth law stated that if two systems are within thermal equilibrium with a third systems, then those two systems are also within equilibrium with each other. The first law states that an increase in energy of a closed system equals the difference of heat supplied by the system and work completed by the reaction. The second law states that heat cannot spontaneously flow from cool to warm. The gradient must flow from warmer to cooler regions. The third law states that when a system approaches absolute zero, the entropy also approaches a minimum value. The entropy defines the unavailable energy of the system and signifies the disorder within the unit. The laws of thermodynamics help explain that energy exists within a closed system. There is only so much energy within that system. There are ways to “tap into” the less available energy, but that using that energy leads to disorder. The laws clearly explain that there is only a specified amount of energy in a system and once this energy is used, there is no more. This means that there has to be some amount of energy conservation in order to guarantee that there remains available energy within the system. There are also various types of energy. Even though energy is converted from one form to another, the same amount of energy is present, independent of the type. Fossil...
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...[pic] |Activity 1.3.3 Thermodynamics | Introduction Think back to the last time someone complained about a door being left open. What did you notice about the temperature within the room as a result of the open door? In Activity 1.3.3 you will investigate the effects of work, thermo energy, and energy on a system, as in the case of the room with the door left open. Procedure Answer the following questions as your teacher discusses the Introduction to Thermodynamics presentation. 1. Define thermodynamics. 2. List three examples of a thermodynamic system. a. b. c. 3. Define thermal energy. 4. Define temperature. |Scale |Freezing point of water |Boiling point of water | |Celsius | | | |Fahrenheit | | | |Kelvin | | | 5. Fill in the table below with the correct scale and unit. ...
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...Centre for Foundation Studies, UTAR 1 2 Chapter Scopes • Endothermic & Exothermic reactions • Enthalpy changes: ∆H of formation, combustion, hydration, neutralization, atomization. CHAPTER 5 Chemical Energetic / Thermochemistry • Lattice energy, electron affinity • Heat of fusion and vaporization • Hess’ Law • Born-Haber cycles • Calorimetry © 2006 Brooks/Cole - Thomson © 2006 Brooks/Cole - Thomson 3 Energy & Chemistry 4 Thermochemistry • Thermochemistry is the study of heat (energy) change/transfer in a chemical reaction. • ENERGY is the capacity to do work or transfer heat. • HEAT is the transfer of thermal energy between two objects because of their difference in temperature. Heat energy is associated with molecular motions. Other forms of energy light electrical kinetic and potential Heat transfers until thermal equilibrium is established. ∆T measures energy transferred. © 2006 Brooks/Cole - Thomson © 2006 Brooks/Cole - Thomson System and Surroundings 5 System and Surroundings 6 Vacuum jacket • SYSTEM – The object under study • SURROUNDINGS – Everything outside the system © 2006 Brooks/Cole - Thomson FHSC1114 Physical Chemistry open Exchange: mass & energy closed energy isolated nothing © 2006 Brooks/Cole - Thomson 1 Centre for Foundation Studies, UTAR Directionality of Heat Transfer 7 Directionality of Heat Transfer • Heat always transfer...
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...Centre for Foundation Studies, UTAR 1 2 Chapter Scopes • Endothermic & Exothermic reactions • Enthalpy changes: ∆H of formation, combustion, hydration, neutralization, atomization. CHAPTER 5 Chemical Energetic / Thermochemistry • Lattice energy, electron affinity • Heat of fusion and vaporization • Hess’ Law • Born-Haber cycles • Calorimetry © 2006 Brooks/Cole - Thomson © 2006 Brooks/Cole - Thomson 3 Energy & Chemistry 4 Thermochemistry • Thermochemistry is the study of heat (energy) change/transfer in a chemical reaction. • ENERGY is the capacity to do work or transfer heat. • HEAT is the transfer of thermal energy between two objects because of their difference in temperature. Heat energy is associated with molecular motions. Other forms of energy light electrical kinetic and potential Heat transfers until thermal equilibrium is established. ∆T measures energy transferred. © 2006 Brooks/Cole - Thomson © 2006 Brooks/Cole - Thomson System and Surroundings 5 System and Surroundings 6 Vacuum jacket • SYSTEM – The object under study • SURROUNDINGS – Everything outside the system © 2006 Brooks/Cole - Thomson FHSC1114 Physical Chemistry open Exchange: mass & energy closed energy isolated nothing © 2006 Brooks/Cole - Thomson 1 Centre for Foundation Studies, UTAR Directionality of Heat Transfer 7 Directionality of Heat Transfer • Heat always transfer...
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... (23) and: K1 and K2 are the rate of forward and backward reaction, respectively. This equation implies that when the rate of reaction is chemically controlled, δ is independent of r and δ, but depends on the concentration of ions in the solution. This equation is applicable if the sorbed ion and counter ion concentration δ are kept constant and the exchange sites are sparsely occupied. 11. Thermodynamic of ion exchange: Thermodynamic is the only thermodynamically precise characteristic of the ion exchange equilibrium. The value is usually calculated with some theoretical assumptions due to the lack of experimental methods to measure activity inside the ion exchanger phase. Gibbs energy of ion exchange is usually calculated with classic Relationship (24) Entropy of the ion exchange reaction is commonly calculated from the Gibbs energy and enthalpy values: (25) Note that H0 and S0 are integral values, i.e. they correspond to complete transfer of the ion exchange from one ionic form to another. This makes them non-sensitive to internal structure of the ion exchanger but limits practical value of the information incorporated in these functions [Soldatov et al., 1972]. ...
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...to harmonize, considering it was our first year learning an instrument. There was no reading or writing when it came to playing the instruments, but with music, a story can be made. For example, half the class would play our recorders in sync with one another, and other students in the class would play percussion. With the rhythm of the music combined, the feel and sound of the music gives the audience a feel of a different environment, such as feeling as though you are taking a journey through an Indian village, or celebrating the first fourth of July in America. As I progressed through the year, music classes turned into singing as well. In order to know the words that we were singing, we had paperback music, which had music lines, notes, and words for us to...
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...through the paper. Halfway through the paper, I saw my friend John suspiciously looking at the class. My instincts told me that something was wrong. As a result, I began to keep an eye on John. Suddenly, I saw John taking notes out from his pencil case! My mouth hung wide open and I gasped in shock. How could John do that! I thought should I report him? The devil in my mind said that I should not care about this thing after all, he is still my best friend while the angel said that I should be honest and report him. After thinking for a while, I decided to report him. I raised my hand and told the teacher “ Mr Tan, John is cheating by using notes from his pencil case.” The teacher nodded his head and walked towards John’s table. Mr Tan said “John! Why are you cheating?” John shook his head to deny that he did not cheat. Mr Tan confiscated his pencil case and dumped the contents out. Out came pencils, erasers and pens. But there was no notes inside! John let out a smirk from his mouth. I was shocked! I thought that there was a note? Just when I thought all hope was lost, Mr Tan found another zip at the pencil case and he opened it. Suddenly, John’s smirk began to vanish. Waves of panic overwhelmed him. The hidden note was found there! Mr Tan looked at John sternly. He brought John to the principal’s office to explain what had happened. On the next day, the fiery-tempered Discipline Master caned John during assembly period. After this incident...
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...and moves to a lower, more thermodynamically stable energy state. The sign convention of changes in free energy follows the general convention for thermodynamic measurements, in which a release of free energy from the system corresponds to a negative change in free energy, but a positive change for the surroundings. A spontaneous process is capable of proceeding in a given direction, as written or described, without needing to be driven by an outside source of energy. The term is used to refer to macro processes in which entropy increases; such as a smell diffusing in a room, ice melting in lukewarm water, salt dissolving in water, and iron rusting. The laws of thermodynamics govern the direction of a spontaneous process, ensuring that if a sufficiently large number of individual interactions (like atoms colliding) are involved then the direction will always be in the direction of increased entropy (since entropy increase is a statistical phenomenon). Entropy is a chemical concept that is very difficult to explain, because a one-sentence definition will not lead to a comprehensive statement. Thus, few people understand what entropy really is. You are not alone if you have some difficulty with this concept. The word entropy is used in many other places and for many other aspects. We confine our discussion to thermodynamics (science dealing with heat and changes) and to chemical and physical processes. We have defined energy as the driving force for changes; entropy is...
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...PMB 103: METABOLISM: BASIC CONCEPTS AND DESIGN Definition of terms; metabolism, bioenergetics and thermodynamics. * Laws of thermodynamics, free energy changes and standard free energy changes in biochemical reactions. * Phosphoryl group transfers and ATP; * Free-energy change for hydrolysis of ATP and other phosphorylated compounds and thioesters. * Role of ATP: phosphorylation, * pyrophosphorylation and adenylation, * assembly of informational macromolecules, * active transport and muscle contraction. * Biological oxidation-reduction reactions; * flow of electrons * dehydrogenations * redox potentials * electron carriers * dehydrogenases * Nature of metabolic reactions: anabolism, catabolism. * regulation of metabolism. Scope of the course * (Review) the laws of thermodynamics and the quantitative relationships among free energy, enthalpy, and entropy. * describe the special role of ATP in biological energy exchanges. Consider the importance of oxidation-reduction reactions in living cells, the energetic of electron-transfer reactions, and the electron carriers commonly employed as cofactors of the enzymes that catalyze these reactions. Reference Books 1. Lehninger, PPls of Biochemistry Fourth Edition David L Nelson and 2. Elementary Biophysics. An introduction. PK. Srivastave Alpha Science Oxford, UK 2005 3. Biophysics. V. Pattabhi and N. Gautham. Second Edition...
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...Moran, M.J. “Engineering Thermodynamics” Mechanical Engineering Handbook Ed. Frank Kreith Boca Raton: CRC Press LLC, 1999 c 1999 by CRC Press LLC Engineering Thermodynamics Michael J. Moran Department of Mechanical Engineering The Ohio State University 2.1 Fundamentals....................................................................2-2 Basic Concepts and Definitions • The First Law of Thermodynamics, Energy • The Second Law of Thermodynamics, Entropy • Entropy and Entropy Generation 2.2 Control Volume Applications.........................................2-14 Conservation of Mass • Control Volume Energy Balance • Control Volume Entropy Balance • Control Volumes at Steady State 2.3 Property Relations and Data ..........................................2-22 Basic Relations for Pure Substances • P-v-T Relations • Evaluating ∆h, ∆u, and ∆s • Fundamental Thermodynamic Functions • Thermodynamic Data Retrieval • Ideal Gas Model • Generalized Charts for Enthalpy, Entropy, and Fugacity • Multicomponent Systems 2.4 2.5 2.6 2.7 Combustion ....................................................................2-58 Reaction Equations • Property Data for Reactive Systems • Reaction Equilibrium Exergy Analysis..............................................................2-69 Defining Exergy • Control Volume Exergy Rate Balance • Exergetic Efficiency • Exergy Costing Vapor and Gas Power Cycles ........................................2-78 Rankine and...
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