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Coagulation and Flocculation

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Coagulation and Flocculation

Conventional Coagulation/Flocculation Process
Pretreatment Chemical Feed Flash Mixing Coagulation & Flocculation Sedimentation Filtration Disinfection

Pretreatment Screen with Cable Raking Mechanism

Pretreatment Considerations
Used prior to Coagulation Addition of oxidizing agents, GAC and polymers Used as far as possible upstream to maximize contact time

Purpose of Coagulation and Flocculation
Remove particulate impurities, especially non-settleable solids, and color from the water being treated. Non-Settleable solids include colloidal material that exhibits slightly negative charges repelling one another and staying in suspension. These contain microbes including pathogens

Pretreatment Considerations in the Coagulation/Flocculation Process
Factors that May Dictate Pretreatment
– Leaves, plant material and silt – Seasonal raw water quality changes caused by drought, high water or temperature changes – Potential upstream pollution – Wind conditions – Algae blooms – Bacterial problems

Removal of Turbidity by Coagulation & Production of Floc
Particle Removal by Coagulation:
Neutralization of repulsive charges Precipitation with sticky flocs Bridging of suspended matter Providing “agglomeration sites” for larger floc Weighting down of floc particles

Factors Affecting the Coagulation Process pH (pH Range: Al, 5 – 7.5 ; Fe, 5 – 8.5); Alkalinity of water (> 30 PPM residual) Concentration of Salts (affect efficiency) Turbidity (constituents and concentration) Type of Coagulant used (Al and Fe salts) Temperature (colder requires more mixing) Adequacy of mixing (dispersion of chemical)

Primary Coagulants
Primary coagulants are lime, aluminum sulfate (alum), ferrous sulfate, ferric sulfate and ferric chloride. These inorganic salts will react with the alkalinity in the water to form insoluble flocs which will trap the suspended matter in them.

Use of Aluminum and Iron Salts in Coagulation
Common Coagulant Chemicals
Aluminum Sulfate Polyaluminum Chloride Sodium Aluminate Ferric Sulfate Ferrous Sulfate Ferric Chloride Al2(SO4)3.14H20 Al(OH)x(CL)y NaAlO 3 Fe 2 (SO4)3 FeSO4 FeCl 3

Considerations in Selection of a Coagulant
Increased Solids: the higher the concentration of the coagulant the more sludge to be disposed of. Dewatering Characteristics: Enhanced coagulation produces a sludge with poor dewatering characteristics Increased Corrosion: The lower the pH the more corrosive the water

Adjusting pH
“Sweep Method” is allowing the coagulant concentration to lower the pH Acid Adjustment: adding acid to lower the pH Enhanced coagulation is lowering of the pH to achieve optimal organic removal.

Use of Alum as a Coagulant
Earliest and Most Widely Used Coagulent Effective Range pH 5.0 to 7.5; Optimal pH for turbidity removal is ~6.5. Optimal pH for color removal is ~5.8. Reacts with Alkalinity Results in drop in pH For every 2 mg/l Alum; 1 mg/l Lime is added

Polyaluminum Chloride
Requires less pH adjustment Produces less sludge than Alum

Use of Iron Salts
Typical pH ranges for turbidity removal is from 5.0 to 8.5 with ~7.5 optimal. Typical range for color removal is 4 to 6.2 with ~4.5 optimal

Use of Ferrous Sulfate (Copperas) and Lime for Coagulation
Combination produces Ferric Hydroxide pH 8.4 range to 9.0 Oxygen must added by aeration or chemically such as chlorine Very Effective for turbid water Care must be taken because color not removed at high pH

Use of Ferric Chloride as a Coagulant
Has wider pH range than Ferrous Sulfate Typically used where color removal is also desirable. Does not require oxygen supplement More effective than Alum in some cases

Use of Ferric Sulfate as a Coagulant
Most effective pH is 4.0 to 6.2 with color removal at ~4.5 Does not require oxygen supplement Effective over wider pH ranges Lower doses required that Ferrous Sulfate

Use of Ferrous Sulfate (Copperas) and Lime for Coagulation
Combination produces Ferric Hydroxide pH 8.4 range to 9.0 Oxygen must added by aeration or chemically such as chlorine Very Effective for turbid water

Secondary Coagulants or Coagulant Aids
Coagulant aids are often added to help stimulate the production of floc. They include sodium aluminate, sodium silicate and various synthetic organic water soluble polyelectrolytes or polymers.

Use of Coagulant Aids
Lime Weighting Agents Polymers

Polyelectrolytes or Polymers use in Water Treatment
Types of Typical Polymers Dosage
Cationic + ~1 ppm

Chemical Constituents and Primary Use
Polydiallyldimethyl and epichlorohydrin

May be used as primary coagulant or more typically coagulant aid Ampholyte 0.005 to Polyacrylamide (+ and -) 0.05 ppm Very high molecular wt. (10X) Anionic Used before filtration and with backwash water

Chemical Feeders
It is important to mix chemicals with fine particles in the water and evenly distribute them. Detention time and the speed of the mixer should be sufficient to thoroughly mix all the chemical with no breakup of floc particles. Baffling The mixing process typically takes less than 20 seconds.

Types of Chemical Mixers
Mechanical devices in a dedicated basin In-line blenders Hydraulic mixing Air mixing Induction mixing

Mixing Coagulants and Coagulant Aids
Rapid/Flash Mix typically occurs in a tank Mixing velocity 5 – 7 fps Coagulant and aids added in first chamber

Flocculation Process
A slow stirring process that causes the gathering together of small particles into larger settleable ones. Controlled by the rate of collisions between particles and the effectiveness promoting attachment.

Flocculation Followed by Sedimentation
Instantaneous mix of coagulants Neutralizes the negative charges on colloids During the gentle mixing of flocculation, allows particles to agglomerate into larger particles Heavier particles are removed by settling

Importance of Flocculator Speed
If the speed of the stirring process is to great then the floc particles will be “sheared” or broken apart causing an increase in turbidity. If flocculator speed is to slow then “shortcircuiting” may occur. Energy gradients should be within 20 to 70 sec-1 Division of flocculator basin is often used to prevent short circuiting 10 to 30 minutes flocculation is a typical detention time in a basin

Desirable Floc Quality
The best floc are smooth circular particles these tend to settle quicker. Irregular shaped particles settle slower. Large clumps (popcorn floc) settle fast but are caused by chemical overdosing.

Performance Monitoring
Flow measurement is important to accurately establish chemical feed rates, wash water rates, and unit loadings Mixing needs to be adequate Chemical feed systems need dosage control Monitor pH for optimum conditions Jar Test at the Start of Every Shift or more!

Performance Measurement Using the Jar Test
A jar test is a laboratory procedure where varying dosages of coagulant are tested in a series of glass or plastic jars under identical conditions. The jars are injected with coagulant dosages and gently paddled or flocculated to match field conditions as closely as possible. After a set of time to simulate field conditions the jars are observed to determine which dosage produces the largest, strongest floc or which dosage produces the floc that settles the fastest. Other laboratory tests sometimes include a jar test to determine the optimal pH or determine the turbidity of the settled water and its filterability.

Factors Affecting the Coagulation Process Revisited pH (pH Range: 5 – 7 for most coagulants) Alkalinity of water (> 30 PPM residual) Concentration of Salts (affect efficiency) Turbidity (constituents and concentration) Type of Coagulant used (Al and Fe salts) Temperature (colder requires more mixing) Adequacy of mixing (dispersion of chemical)

Jar Test Apparatus and Procedures
Six paddles One container is control RPM gauge allows for mixing speed to match plant conditions
Flash Mix: 1 Minute at 80 RPM Flocculation: 30 Minutes at 20 RPM Settling: 30 Minutes

Evaluation of Jar Test Results
Rate of Floc Formation Type of Floc Particles Clarity of the Water between the Floc Size of the Floc Amount of Floc Clarity of Water above Settled Floc Volume of Floc

Jar Test Plot for Low Alkalinity Water
Alum initially reacts with low alkalinity With Ferric Chloride requires chemical to reach optimal pH before reacting Adding too much coagulant increases turbidity

Jar Test Plot for Higher Alkalinity Water
Higher Coagulant doses are needed for high alkalinity waters Ferric Chloride required more chemical but reached lower turbidity Since Alum did not produce water < 1 NTU a coagulant aid is necessary

Additional Analysis for Jar Testing
Alkalinity pH Turbidity of Supernatant Filtered Turbidity of Supernatant

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